| | No | Class | T | Team | Driver | Car | Time |
| 1 | 12 | LMP1 | M | Rebellion Racing | Nicolas Prost
Neel Jani | Lola B10/60
Coupé-Toyota | 1:46.783 |
| 2 | 20 | LMP1 | D | Quifel-ASM Team | Miguel Amaral
Olivier Pla | Zytek 09SC | 1:47.231 |
| 3 | 13 | LMP1 | M | Rebellion Racing | Andrea Belicchi
Jean-Christophe Boullion | Lola B10/60
Coupé-Toyota | 1:48.491 |
| 4 | 46 | LMP2 | M | TDS Racing | Mathias Beche
Pierre Thiriet
Jody Firth | Oreca 03-Nissan | 1:48.928 |
| 5 | 45 | LMP2 | D | Boutsen Energy Racing | Dominik Kraihamer
Nicolas De Crem | Oreca 03-Nissan | 1:49.692 |
| 6 | 41 | LMP2 | D | Greaves Motorsport | Karim Oijeh
Gary Chalandon
Tom Kimber-Smith | Zytek Z11SN-Nissan | 1:50.008 |
| 7 | 40 | LMP2 | D | Race Performance | Michel Frey
Ralph Meichtry
Thor-Christian Ebbesvik | Oreca 03-Judd | 1:50.356 |
| 8 | 39 | LMP2 | M | Pecom Racing | Luis Perez Companc
Matias Russo
Pierre Kaffer | Lola B11/40-Judd | 1:51.744 |
| 9 | 44 | LMP2 | D | Extreme Limite AM Paris | Fabien Rosier
Jean-Pierre Luco
Maurice Basso | Norma M200P-Judd | 1:52.158 |
| 10 | 009 | LMP1 | M | Aston Martin Racing | Stefan Mücke
Darren Turner
Harold Primat | Aston Martin AMR-One | 1:52.267 |
| 11 | 43 | LMP2 | P | Team RLR | Barry Gates
Rob Garofall
Simon Phillips | MG Lola EX265-HPD | 1:53.414 |
| 12 | 42 | LMP2 | M | Strakka Racing | Nick Leventis
Danny Watts
Jonny Kane | HPD ARX-01 | 1:53.582 |
| 14 | 91 | FLM | M | Hope Polevision Racing | Luca Moro
Michael Tinguely
Zhang Shanqi | Formula Le Mans-
Oreca - 09 | 1:53.659 |
| 14 | 93 | FLM | M | Genoa Racing | Jens Petersen
Elton Julian
Christian Zugel | Formula Le Mans-
Oreca - 09 | 1:54.044 |
| 15 | 92 | FLM | M | Neil Garner Motorsport | John Hartshorne
Steve Keating
Phil Keen | Formula Le Mans-
Oreca - 09 | 1:54.081 |
| 16 | 95 | FLM | M | Pegasus Racing | Mirco Schultis
Patrick Simon
Julien Schell | Formula Le Mans-
Oreca - 09 | 1:55.829 |
| 17 | 99 | FLM | M | JMB Racing | Manuel Rodrigues
Nicolas Misslin
Jean-Marc Menahem | Formula Le Mans-
Oreca - 09 | 1:56.806 |
| 18 | 51 | GTE PRO | M | AF Corse | Giancarlo Fisichella
Gianmaria Bruni | Ferrari F458 Italia | 1:58.522 |
| 19 | 86 | GTE PRO | M | Young Driver AMR | Tomáš Enge
Alex Müller
Christoffer Nygaard | Aston Martin Vantage | 1:58.773 |
| 20 | 66 | GTE PRO | D | JMW Motorsport | Rob Bell
James Walker | Ferrari F458 Italia | 1:59.119 |
| 21 | 71 | GTE PRO | M | AF Corse | Jaime Melo
Toni Vilander | Ferrari F458 Italia | 1:59.144 |
| 22 | 89 | GTE PRO | H | Hankook-Team Farnbacher | Dominik Farnbacher
Allan Simonsen | Ferrari F458 Italia | 1:59.244 |
| 23 | 75 | GTE PRO | M | Prospeed Competition | Marco Holzer
Marc Goossens | Porsche 997 GT3 RSR | 1:59.244 |
| 24 | 67 | GTE AM | M | IMSA Performance Matmut | Raymond Narac
Nicolas Armindo | Porsche 997 GT3 RSR | 1:59.370 |
| 25 | 77 | GTE PRO | M | Team Felbermayr Proton | Marc Lieb
Richard Lietz | Porsche 997 GT3 RSR | 1:59.455 |
| 26 | 76 | GTE PRO | M | IMSA Performance Matmut | Patrick Pilet
Wolf Henzler | Porsche 997 GT3 RSR | 1:59.457 |
| 27 | 79 | GTE PRO | D | Jota Sport AMR | Sam Hancock
Simon Dolan | Aston Martin Vantage | 2:00.336 |
| 28 | 88 | GTE AM | M | Team Felbermayr Proton | Horst Felbermayer Sr
Christian Ried
Horst Felbermayer Jr | Porsche 997 GT3 RSR | 2:00.354 |
| 29 | 61 | GTE AM | M | AF Corse | Piergiuseppe Perazzini
Marco Cioci
Stéphane Lémeret | Ferrari F430 GT2 | 2:00.470 |
| 30 | 70 | GTE AM | M | Kessel Racing | Michael Broniszewski
Philipp Peter | Ferrari F430 GT2 | 2:00.698 |
| 31 | 82 | GTE AM | M | CRS Racing | Klaas Hummel
Adam Christodoulou
Phil Quaife | Ferrari F430 GT2 | 2:01.137 |
| 32 | 72 | GTE AM | M | AF Corse | Robert Kauffman
Rui Aguas
Guiseppe Ciro | Ferrari F430 GT2 | 2:01.691 |
| 33 | 16 | LMP1 | M | Pescarolo Sport | Emmanuel Collard
Christophe Tinseau
Julien Jousse | Pescarolo 01-Judd | 1:47.025(DQ) |
| 34 | 36 | LMP2 | D | RML | Mike Newton
Tommy Erdos
Ben Collins | HPD ARX-01d | No Time |
