| | No. | Class | Team | Driver | Car | |
| 1 | 8 | LMP1 | Team Peugeot Total | Pedro Lamy
Stephane Sarrazin | Peugeot 908 HDi-FAP | 1.31.875 |
| 2 | 7 | LMP1 | Team Peugeot Total | Marc Gene
Nicolas Minassian | Peugeot 908 HDi-FAP | 1.32.454 |
| 3 | 1 | LMP1 | Audi Sport Team Joest | Allan McNish
Rinaldo Capello | Audi R10 TDI | 1.33.250 |
| 4 | 10 | LMP1 | Charouz Racing System | Stefan Mucke
Jan Charouz | Lola B06/80-Aston Martin | 1.33.734 |
| 5 | 34 | LMP2 | Van Merksteijn Motorsport | Peter van Merksteijn
Jos Verstappen | Porsche RS-Spyder | 1.34.422 |
| 6 | 2 | LMP1 | Audi Sport Team Joest | Alexandre Premat
Mike Rockenfeller | Audi R10 TDI | 1.34.671 |
| 7 | 6 | LMP1 | Team Oreca Matmut | Olivier Panis
Nicolas Lapierre | Courage-Oreca LC70-Judd | 1.35.070 |
| 8 | 16 | LMP1 | Pescarolo Sport | Emmanuel Collard
Jean-Christophe Boullion | Pescarolo-Judd | 1.35.641 |
| 9 | 33 | LMP2 | Speedy Racing Team Sebah | Andrea Belicchi
Steve Zacchia
Xavier Pompidou | Lola B08/80 Coupe-Judd | 1.35.797 |
| 10 | 27 | LMP2 | Horag Racing | Fredy Lienhard
Didier Theys
Jan Lammers | Porsche RS-Spyder | 1.36.156 |
| 11 | 31 | LMP2 | Team Essex | John Nielsen
Casper Elgaard | Porsche RS-Spyder | 1.36.266 |
| 12 | 14 | LMP1 | Creation AIM | Jamie Campbell-Walter
Felipe Ortiz
Stuart Hall | Creation CA07-AIM | 1.36.375 |
| 13 | 17 | LMP1 | Pesarolo Sport | Harold Primat
Christophe Tinseau | Pescarolo-Judd | 1.36.516 |
| 14 | 18 | LMP1 | Rollcentre Racing | Joao Barbosa
Vanina Ickx
Martin Short | Pescarolo-Judd | 1.36.640 |
| 15 | 40 | LMP2 | Quifel-ASM Team | Miguel Amaral
Olivier Pla | Lola B050/40-AER | 1.36.641 |
| 16 | 5 | LMP1 | Team Oreca Matmut | Stephane Ortelli
Soheil Ayari | Courage-Oreca LC70-Judd | 1.36.797 |
| 17 | 20 | LMP1 | Epsilon-Euskadi | Angel Burgueno
Miguel Angel de Castro | Epsilon Euskadi ee1-Judd | 1.36.922 |
| 18 | 32 | LMP2 | Barazi-Epsilon | Juan Barazi
Michael Vergers | Zytek 07S-Zytek | 1.37.516 |
| 19 | 45 | LMP2 | Embassy Racing | Warren Hughes
Mario Haberfeld | WF01-Zytek | 1.38.109 |
| 20 | 44 | LMP2 | Kruse Schiller Motorsport | Jean de Pourtales
Hideki Noda | Lola B05/40-Mazda | 1.38.437 |
| 21 | 25 | LMP2 | RML | Tommy Erdos
Mike Newton | MG Lola EX265-MG | 1.38.485 |
| 22 | 46 | LMP2 | Embassy Racing | Jonny Kane
Joey Foster | WF01-Zytek | 1.38.500 |
| 23 | 19 | LMP1 | Chamberlain Synergy | Gareth Evans
Bob Berridge
Amanda Stretton | Lola B06/10-AER | 1.39.063 |
| 24 | 35 | LMP2 | Saulnier Racing | Pierre Ragues
Matthieu Lahaye | Pescarolo-Judd | 1.39.594 |
| 25 | 4 | LMP1 | Saulnier Racing | Jacques Nicolet
Marc Faggionato
Richard Hein | Pescarolo-Judd | 1.40.594 |
| 26 | 26 | LMP2 | Bruichladdich Radical | Marc Rostan
Jens Petersen
Jan-Dirk Lueders | Radical SR9 -AER | 1.40.750 |
| 27 | 41 | LMP2 | Trading Performance | Karim Ojjeh
Claude-Yves Gosselin
Julien Schroyen | Zytek 07S-Zytek | 1.41.516 |
| 28 | 3 | LMP1 | Scuderia Lavaggi | Giovanni Lavaggi
Wolfgang Kaufmann | Lavaggi LS1-AER | 1.41.610 |
| 29 | 59 | GT1 | Team Modena | Antonio Garcia
Tomas Enge | Aston Martin DBR9 | 1.44.484 |
| 30 | 72 | GT1 | Luc Alphand Aventures | Luc Alphand
Guillaume Moreau
Patrice Goueslard | Corvette C6.R | 1.44.531 |
| 31 | 30 | LMP2 | Racing Box | Marco Didaio
Filippo Francioni | Lucchini-Judd | 1.44.579 |
| 32 | 55 | GT1 | IPB Spartak Racing | Roman Rusinov
Peter Kox | Lamborghini Murcielago R-GT | 1.44.969 |
| 33 | 73 | GT1 | Luc Alphand Aventures | Sebastien Dumez
Jean-Luc Blanchemain
Roland Berville | Corvette C6.R | 1.46.718 |
| 34 | 96 | GT2 | Virgo Motorsport | Robert Bell
Gianmaria Bruni | Ferrari F430 GT | 1.47.844 |
| 35 | 77 | GT2 | Team Felbermayr Proton | Marc Lieb
Alex Davison | Porsche 997 GT3 RSR | 1.49.093 |
| 36 | 76 | GT2 | IMSA Performance Matmut | Raymond Narac
Richard Lietz | Porsche 997 GT3 RSR | 1.49.250 |
| 37 | 91 | GT2 | Farnbacher Racing | Lars Erik Nielsen
Allan Simonsen
Richard Westbrook | Porsche 997 GT3 RSR | 1.49.250 |
| 38 | 90 | GT2 | Farnbacher Racing | Pierre Ehret
Pierre Kaffer
Anthony Beltoise | Ferrari F430 GT | 1.49.343 |
| 39 | 75 | GT2 | IMSA Performance Matmut | Richard Balandras
Michel Lecourt
Jean-Philippe Belloc | Porsche 997 GT3 RSR | 1.49.593 |
| 40 | 37 | LMP2 | WR/Salini | Stephane Salini
Philippe Salini
Patrice Roussel | WR-Zytek | 1.49.859 |
| 41 | 99 | GT2 | JMB Racing | Stephane Daoudi
Ben Aucott | Ferrari F430 GT | 1.50.297 |
| 42 | 94 | GT2 | Speedy Racing Team | Andrea Chiesa
Benjamin Leuenberger | Spyker C8 Laviolette GT2R | 1.50.953 |
| 43 | 85 | GT2 | Snoras Spyker Squadron | Peter Dumbreck
Ralf Kelleners
Alexei Vasiliev | Spyker C8 Laviolette GT2R | 1.50.953 |
| 44 | 93 | GT2 | James Watt Automotive | Alan van der Merwe
Stephane Lemeret
Michael Outzen
| Aston Martin Vantage V8 | 1.51.015 |
| 45 | 88 | GT2 | Team Felbermayr Proton | Horst Felbermayr Jr
Christian Ried
Horst Felbermayr Sr | Porsche 997 GT3 RSR | 1.51.218 |
| 46 | 95 | GT2 | James Watt Automotive | Markus Palttala
Paul Daniels
Mikael Forsten | Porsche 997 GT3 RSR | 1.51.250 |
| 47 | 98 | GT2 | JMB Racing | Maurice Basso
Bo McCormick
Mauro Casadei | Ferrari F430 GT | 1.52.078 |
| 48 | 50 | GT1 | Larbre Competition | Frederic Makowiecki
Patrick Bornhauser
Christophe Bouchut | Saleen S7R-Ford | no time |
