| Pos | No | Class | Tyres | Team | Driver | Car | Time |
| 1 | 2 | GT2 | M | AF Corse - ALD Team Vitaphone | Gimmi Bruni
Bert Longin
Eric van de Poele
Toni Vilander | Ferrari 430 GT2 | 2:22.403 |
| 2 | 79 | GTN | D | BMW Motorsport | Dirk Werner
Dirk Müller
Dirk Andorf | BMW M3 | 2:22.549 |
| 3 | 50 | GT3 | M | Phoenix Racing | Anthony Kumpen
Marcel Fässler
Lucas Luhr
Mike Rockenfeller | Audi R8 LMS | 2:22.807 |
| 4 | 51 | GT3 | M | Phoenix Racing | Alex Margaritis
Marc Hennerici
Andrea Piccini
Henri Moser | Audi R8 LMS | 2:23.022 |
| 5 | 84 | GT3 | M | Reiter Engineering | Peter Kox
Marc Hayek
Ettore Bonaldi
Jeffrey Lee | Lamborghini LP560-4 | 2:23.252 |
| 6 | 78 | GTN | D | BMW Motorsport | Jörg Müller
Pedro Lamy
Uwe Alzen | BMW M3 | 2:23.531 |
| 7 | 16 | GT2 | M | IMSA Performance Matmut | Raymond Narac
Pat Long
Patrick Pilet
Richard Lietz | Porsche 911 GT3 RS (997) | 2:23.960 |
| 8 | 13 | GT2 | M | ProSpeed Competition | Richard Westbrook
Marco Holzer
Marc Lieb
Marc Goossens | Porsche 911 GT3 RS (997) | 2:24.456 |
| 9 | 73 | GT3 | M | WRT Belgian Audi Club | Stéphane Ortelli
Stéphane Lemeret
Francois Verbist
Kurt Mollekens | Audi R8 LMS | 2:24.659 |
| 10 | 60 | GT3 | M | ProSpeed Competition | Oskar Slingerland
Maxime Soulet
Julien Schroyen
Jos Menten | Porsche 911 GT3 R | 2:24.775 |
| 11 | 23 | GT2 | M | BMS Scuderia Italia | Romain Dumas
Jörg Bergmeister
Martin Ragginger
Wolf Henzler | Porsche 911 GT3 RS (997) | 2:24.887 |
| 12 | 99 | GT3 | M | Marc VDS Racing | Bas Leinders
Maxime Martin
Marc Duez | Ford GT | 2:25.270 |
| 13 | 72 | GT3 | M | WRT Belgian Audi Club | Greg Franchi
Vincent Vosse
Frank Biela
Frank Stippler | Audi R8 LMS | 2:25.388 |
| 14 | 74 | GT3 | M | WRT Belgian Audi Club | Fred Bouvy
Christian Kelders
David Tuchbant
Jean-Luc Blanchemain | Audi R8 LMS | 2:25.702 |
| 15 | 61 | GT3 | M | ProSpeed Competition | Remy Brouard
Philippe Noziere
Christophe Kerkhove
Ludovic Sougnez | Porsche 911 GT3 R | 2:25.706 |
| 16 | 68 | GT3 | M | United Autosports | Richard Dean
Zak Brown
Eddie Cheever
Mark Blundell | Audi R8 LMS | 2:25.745 |
| 17 | 81 | GTN | M | Gravity International | Romain Grosjean
Vincent Radermacker
Diego Alessi
Ron Marchal | Mosler MT 900 | 2:25.764 |
| 18 | 86 | GT3 | M | Gulf Team First | Didier André
Grégoire de Moustier
Mike Wainwright
Roald Goethe | Lamborghini LP560-4 | 2:25.964 |
| 19 | 1 | GT2 | M | AF Corse - ALD Team Vitaphone | Michael Waltrip
Niki Cadei
Robert Kauffman
Marco Cioci | Ferrari 430 GT2 | 2:27.072 |
| 20 | 98 | GT3 | M | Marc VDS Racing | Eric de Doncker
Renaud Kuppens
Markus Paltalla | Ford GT | 2:27.193 |
| 21 | 67 | GT3 | M | United Autosports | Stefan Johansson
Emil Assentato
Mark Patterson
Alan Li | Audi R8 LMS | 2:27.220 |
| 22 | 4 | GT2 | M | ProSpeed Competition | Paul van Splunteren
Niek Hommerson
Louis Machiels
Phil Bastiaans | Porsche 911 GT3 RS (997) | 2:27.488 |
| 23 | 56 | GT3 | M | Sport Garage | André-Alain Corbel
Thomas Duchene
Christian Beroujon
Salam Bernard | BMW Alpina B6 GT3 | 2:28.826 |
| 24 | 17 | GT2 | M | IMSA Performance Matmut | Christophe Bourret
Pascal Gibon
Jean-Phillippe Belloc
Richard Balandras | Porsche 911 GT3 RS (997) | 2:28.983 |
| 25 | 71 | GT3 | M | Team RPM | Alex Mortimer
Peter Bamford
Matt Griffin | Ford GT | 2:29.203 |
| 26 | 7 | GT2 | A | Trackspeed | David Ashburn
Carl Rosenblad
Sebastien Asch
Tim Bergmeister | Porsche 911 GT3 RS (997) | 2:29.328 |
| 27 | 85 | GT3 | M | Gulf Team First | Fabien Giroix
Anthony Beltoise
Frédéric Fatien
Jean-Pierre Valentini | Lamborghini LP560-4 | 2:29.366 |
| 28 | 64 | GT3 | M | Brussels Racing | Eddy Renard
Tim Verbergt
Koen Wauters
Jeff Van Hooydonk | Aston Martin DBRS9 | 2:29.978 |
| 29 | 55 | GT3 | M | Sport Garage | Romain Brandela
Gael Lesoudier
Thierry Pignaud
Thierry Stepec | BMW Alpina B6 GT3 | 2:30.147 |
| 30 | 53 | GT3 | M | Mühlner Motorsport | Jürgen Häring
Dimitrios Konstantinou
Arnaud Peyroles
Gilles Vannelet | Porsche 911 GT3 R | 2:30.761 |
| 30 | 66 | GTN | M | Jetalliance Racing | Lukas Lichtner Hoyer
Vitus Eckert
Marco Seefried
Martin Rich | Porsche 997 GT3 Cup MY06 | 2:30.761 |
| 32 | 52 | GT3 | M | Mühlner Motorsport | Armand Fumal
Gianluca De Lorenzi
Jêrome Thiry
Mark J. Thomas | Porsche 911 GT3 R | 2:31.199 |
| 33 | 100 | GTN | M | First Motorsport | Raymond Coronel
Jeroen Schothorst
Hoevert Vos
Harrie Kolen | Porsche 997 GT3 Cup S | 2:31.351 |
| 34 | 92 | GTN | M | G2 Racing | Björn Grossman
Claudio Sdanewitsch
Stéphane Clareton
Cédric Mézard | Ferrari F430 | 2:32.729 |
| 35 | 58 | GTN | M | VDS Racing Adventures | Raphael Van de Straten
Karim Al Azhari
Jose Close
Erik Qvick | Ford Mustang FR500C-GT | 2:37.182 |
| 36 | 62 | GT4 | M | RJN Motorsport | Rob Barff
Lucas Ordonez
Alex Buncombe
Chris Buncombe | Nissan 370Z | 2:39.099 |
| 37 | 59 | GT4 | M | Jota Sport | Simon Dolan
Sam Hancock
Roger Wills
Joe Twyman | Aston Martin V8 Vantage | 2:40.789 |
| 38 | 63 | GT3 | M | Brussels Racing | Christophe D'Ansembourg
Pierre Grivegnée
Jérôme Demay
Pierre Merche | Aston Martin DBRS9 | 2:43.154 |
| 39 | 91 | GTN | M | Level Racing | Brody
René Marin
Bruno Barbaro
Christoff Corten | Porsche 997 Cup | 2:43.349 |
| 40 | 70 | GT4 | M | Speedlover | Sebastien Viale
Michel de Coster
Rik Renmans
Pascal NelissenGrade | Porsche 997 GT3 MY06 | 2:48.881 |
| 41 | 69 | GT4 | M | Speedlover | Patrick Deblauwe
René Brugmans
Didier Grandjean
Jean-Michel Gérome | Porsche 997 GT3 MY06 | 2:54.081 |
| 42 | 87 | GT3 | M | Argo Racing | TBA | Lamborghini LP560-4 | No time |
