| | No | Class | T | Team | Driver | Car | Time |
| 1 | 6 | LMP1 | D | Team Oreca Matmut | Soheil Ayari Andy Meyrick Didier Andre | Oreca 01-AIM | 1:44.954 |
| 2 | 13 | LMP1 | M | Rebellion Racing | Andrea Belicchi Jean-Christophe Boullion Guy Smith | Lola B10/60 Coupé-Rebellion | 1:45.069 |
| 3 | 4 | LMP1 | M | Team Oreca Matmut | Olivier Panis Nicolas Lapierre Loic Duval | Peugeot 908 HDi FAP | 1:45.280 |
| 4 | 5 | LMP1 | D | Beechdean Mansell | Nigel Mansell Leo Mansell Greg Mansell | Ginetta-Zytek GZ09S-Zytek | 1:45.662 |
| 5 | 008 | LMP1 | D | Signature Plus | Pierre Ragues Frank Mailleux | Lola Aston Martin | 1:46.213 |
| 6 | 009 | LMP1 | M | Aston Martin Racing | Harold Primat Adrian Fernandez Darren Turner Stefan Mücke | Lola Aston Martin | 1:46.901 |
| 7 | 42 | LMP2 | M | Strakka Racing | Nick Leventis Danny Watts Jonny Kane | HPD ARX-01 | 1:47.378 |
| 8 | 40 | LMP2 | D | Quifel-ASM Team | Miguel Amaral Olivier Pla Warren Hughes | Ginetta-Zytek 09S-Zytek | 1:47.981 |
| 9 | 25 | LMP2 | D | RML | Tommy Erdos Mike Newton Andy Wallace | Lola HPD Coupé | 1:48.958 |
| 10 | 35 | LMP2 | D | Oak Racing | Matthieu Lahaye Guillaume Moreau | Pescarolo-Judd | 1:50.283 |
| 11 | 41 | LMP2 | D | Team Bruichladdich | Karim Oijeh Tim Greaves Thor-Chrsitian Ebbesvik | Ginetta-Zytek 09S-Zytek | 1:51.074 |
| 12 | 12 | LMP1 | M | Rebellion Racing | Nicolas Prost Neel Jani Marco Andretti | Lola B10/60 Coupé-Rebellion | 1:51.359 |
| 13 | 30 | LMP2 | P | Racing Box | Andrea Piccini Giacomo Piccini Jesus Diego Villarroel Ferdinando Geri | Lola B09 Coupé-Judd | 1:52.526 |
| 14 | 24 | LMP2 | D | Oak Racing | Richard Hein Jacques Nicolet | Pescarolo-Judd | 1:53.042 |
| 15 | 29 | LMP2 | P | Racing Box | Piergiuseppe Perazzini Marco Cioci Luca Pirri | Lola B09 Coupé-Judd | 1:54.301 |
| 16 | 45 | LMP2 | M | Boutsen Energy Racing | Dominik Kraihamer Nicolas De Crem Norbert Lenzenverger Antoine Leclerc | Formula Le Mans-Oreca 09 | 1:54.352 |
| 17 | 39 | LMP2 | D | KSM | Jean De Pourtales Jonathon Hirschi Stéphane Lemeret Hideki Noda Valentin Hummel | Lola B08/47-Judd | 1:55.265 |
| 18 | 49 | LMP2 | M | Applewood Seven | Damien Toulemonde Vincent Capillaire Philippe Bourgois | Formula Le Mans | 1:56.065 |
| 19 | 27 | LMP2 | D | Race Performance | Michel Frey Ralph Meichtry | Radical SR9 -Judd | 1:56.478 |
| 20 | 61 | GT1 | M | Matech Competition | Thomas Mutsch Natach Gachnang Cindy Allemann Rahel Frey Enrique Bernoldi | Ford GT | 1:59.582 |
| 21 | 92 | GT2 | D | JMW Motorsport | Rob Bell Tim Sugden | Aston Martin V8 Vantage | 1:59.649 |
| 22 | 70 | GT1 | M | Marc VDS Racing Team | Bas Leinders Maxime Martin Eric De Donker | Ford GT | 1:59.817 |
| 23 | 52 | GT1 | M | Young Driver AMR | Darren Turner Christoffer Nygaard | Aston Martin DBR9 | 1:59.853 |
| 24 | 96 | GT2 | M | AF Corse | Gianmaria Bruni Jaime Melo | Ferrari F430 GT | 1:59.901 |
| 25 | 43 | LMP2 | M | DAMS | Gary Chalandon Andrea Barlesi Alessandro Cicognani Laurens Vanthoor | Formula Le Mans-Oreca 09 | 1:59.919 |
| 26 | 89 | GT2 | H | Hankook-Team Farnbacher | Dominik Farnbacher Allan Simonsen | Ferrari F430 GT | 2:00.155 |
| 27 | 95 | GT2 | M | AF Corse | Giancarlo Fisichella Toni Vilander Jean Alesi | Ferrari F430 GT | 2:00.243 |
| 28 | 91 | GT2 | M | CRS Racing | Andrew Kirkaldy Tim Mullen Nicola Larini | Ferrari F430 GT | 2:00.594 |
| 29 | 50 | GT1 | M | Larbre Competition | Gabriel Gardel Patrice Goueslard Julien Canal | Saleen S7R | 2:00.667 |
| 30 | 76 | GT2 | M | IMSA Performance Matmut | Raymond Narac Patrick Pilet | Porsche 997 GT3 RSR | 2:00.806 |
| 31 | 94 | GT2 | M | AF Corse | Luis Perez Companc Matias Russo | Ferrari F430 GT | 2:00.884 |
| 32 | 75 | GT2 | M | Prospeed Competition | Marco Holzer Richard Westbrook | Porsche 997 GT3 RSR | 2:01.150 |
| 33 | 68 | GT1 | M | Marc VDS Racing Team | Renaud Kuppens Markus Palttala | Ford GT | 2:01.376 |
| 34 | 77 | GT2 | M | Team Felbermayr Proton | Marc Lieb Richard Lietz Christian Ried | Porsche 997 GT3 RSR | 2:01.709 |
| 35 | 90 | GT2 | M | CRS Racing | Pierre Ehret Phil Quaife Pierre Kaffer | Ferrari F430 GT | 2:02.263 |
| 36 | 78 | GT2 | D | BMW Team Schnitzer | Jörg Müller Dirk Werner Uwe Altzen | BMW M3 | 2:02.813 |
| 37 | 46 | LMP2 | M | JMB Racing | Peter Kutemann Maurice Basso John Hartshorne Fabien Rosier Corentine Quiniou | Formula Le Mans-Oreca 09 | 2:03.663 |
| 38 | 87 | GT2 | M | IMSA Performance Matmut | Richard Balandras Pascal Gibon Christophe Bourret | Porsche 997 GT3 RSR | 2:04.763 |
| 39 | 47 | LMP2 | M | Hope Polevision Racing | Steve Zacchia Michael Tinguely Olivier Lombard Jeff Collier | Formula Le Mans | No Time |
| 40 | 48 | LMP2 | M | Hope Polevision Racing | Mathias Beche Christophe Pillon | Formula Le Mans | No Time |
| 41 | 44 | LMP2 | M | DAMS | Guillaume Bermond Nelson Pantiatici Dean Stirling | Formula Le Mans-Oreca 09 | No Time |