| | No | Class | T | Team | Driver | Car | Time |
| 1 | 6 | LMP1 | D | Team Oreca Matmut | Soheil Ayari
Andy Meyrick
Didier Andre | Oreca 01-AIM | 1:42.963 |
| 2 | 12 | LMP1 | M | Rebellion Racing | Nicolas Prost
Neel Jani
Marco Andretti | Lola B10/60 Coupé-Rebellion | 1:44.025 |
| 3 | 13 | LMP1 | M | Rebellion Racing | Andrea Belicchi
Jean-Christophe Boullion
Guy Smith | Lola B10/60 Coupé-Rebellion | 1:44.264 |
| 4 | 008 | LMP1 | D | Signature Plus | Pierre Ragues
Frank Mailleux | Lola Aston Martin | 1:44.502 |
| 5 | 4 | LMP1 | M | Team Oreca Matmut | Olivier Panis
Nicolas Lapierre
Loic Duval | Peugeot 908 HDi FAP | 1:44.594 |
| 6 | 009 | LMP1 | M | Aston Martin Racing | Harold Primat
Adrian Fernandez
Darren Turner
Stefan Mücke | Lola Aston Martin | 1:45.342 |
| 7 | 40 | LMP2 | D | Quifel-ASM Team | Miguel Amaral
Olivier Pla
Warren Hughes | Ginetta-Zytek 09S-Zytek | 1:46.584 |
| 8 | 42 | LMP2 | M | Strakka Racing | Nick Leventis
Danny Watts
Jonny Kane | HPD ARX-01 | 1:47.239 |
| 9 | 25 | LMP2 | D | RML | Tommy Erdos
Mike Newton
Andy Wallace | Lola HPD Coupé | 1:47.313 |
| 10 | 30 | LMP2 | P | Racing Box | Andrea Piccini
Giacomo Piccini
Jesus Diego Villarroel
Ferdinando Geri | Lola B09 Coupé-Judd | 1:49.063 |
| 11 | 29 | LMP2 | P | Racing Box | Piergiuseppe Perazzini
Marco Cioci
Luca Pirri | Lola B09 Coupé-Judd | 1:49.335 |
| 12 | 35 | LMP2 | D | Oak Racing | Matthieu Lahaye
Guillaume Moreau | Pescarolo-Judd | 1:49.769 |
| 13 | 24 | LMP2 | D | Oak Racing | Richard Hein
Jacques Nicolet | Pescarolo-Judd | 1:50.233 |
| 14 | 41 | LMP2 | D | Team Bruichladdich | Karim Oijeh
Tim Greaves
Thor-Chrsitian Ebbesvik | Ginetta-Zytek 09S-Zytek | 1:50.403 |
| 15 | 5 | LMP1 | D | Beechdean Mansell | Nigel Mansell
Leo Mansell
Greg Mansell | Ginetta-Zytek GZ09S-Zytek | 1:51.431 |
| 16 | 39 | LMP2 | D | KSM | Jean De Pourtales
Jonathon Hirschi
Stéphane Lemeret
Hideki Noda
Valentin Hummel | Lola B08/47-Judd | 1:52.198 |
| 17 | 48 | LMP2 | M | Hope Polevision Racing | Mathias Beche
Christophe Pillon | Formula Le Mans | 1:54.253 |
| 18 | 44 | LMP2 | M | DAMS | Guillaume Bermond
Nelson Pantiatici
Dean Stirling | Formula Le Mans-Oreca 09 | 1:55.085 |
| 19 | 49 | LMP2 | M | Applewood Seven | Damien Toulemonde
Vincent Capillaire
Philippe Bourgois | Formula Le Mans | 1:55.643 |
| 20 | 43 | LMP2 | M | DAMS | Gary Chalandon
Andrea Barlesi
Alessandro Cicognani
Laurens Vanthoor | Formula Le Mans-Oreca 09 | 1:56.075 |
| 21 | 46 | LMP2 | M | JMB Racing | Peter Kutemann
Maurice Basso
John Hartshorne
Fabien Rosier
Corentine Quiniou | Formula Le Mans-Oreca 09 | 1:56.578 |
| 22 | 47 | LMP2 | M | Hope Polevision Racing | Steve Zacchia
Michael Tinguely
Olivier Lombard
Jeff Collier | Formula Le Mans | 1:57.243 |
| 23 | 61 | GT1 | M | Matech Competition | Thomas Mutsch
Natach Gachnang
Cindy Allemann
Rahel Frey
Enrique Bernoldi | Ford GT | 1:58.243 |
| 24 | 52 | GT1 | M | Young Driver AMR | Darren Turner
Christoffer Nygaard | Aston Martin DBR9 | 1:58.819 |
| 25 | 91 | GT2 | M | CRS Racing | Andrew Kirkaldy
Tim Mullen
Nicola Larini | Ferrari F430 GT | 1:59.272 |
| 26 | 96 | GT2 | M | AF Corse | Gianmaria Bruni
Jaime Melo | Ferrari F430 GT | 1:59.754 |
| 27 | 68 | GT1 | M | Marc VDS Racing Team | Renaud Kuppens
Markus Palttala | Ford GT | 1:59.842 |
| 28 | 94 | GT2 | M | AF Corse | Luis Perez Companc
Matias Russo | Ferrari F430 GT | 1:59.907 |
| 29 | 77 | GT2 | M | Team Felbermayr Proton | Marc Lieb
Richard Lietz
Christian Ried | Porsche 997 GT3 RSR | 1:59.976 |
| 30 | 75 | GT2 | M | Prospeed Competition | Marco Holzer
Richard Westbrook | Porsche 997 GT3 RSR | 2:00.247 |
| 31 | 92 | GT2 | D | JMW Motorsport | Rob Bell
Tim Sugden
Darren Turner | Aston Martin V8 Vantage | 2:00.525 |
| 32 | 95 | GT2 | M | AF Corse | Giancarlo Fisichella
Toni Vilander
Jean Alesi | Ferrari F430 GT | 2:00.862 |
| 33 | 76 | GT2 | M | IMSA Performance Matmut | Raymond Narac
Patrick Pilet | Porsche 997 GT3 RSR | 2:01.509 |
| 34 | 90 | GT2 | M | CRS Racing | Pierre Ehret
Phil Quaife
Pierre Kaffer | Ferrari F430 GT | 2:02.209 |
| 35 | 27 | LMP2 | D | Race Performance | Michel Frey
Ralph Meichtry | Radical SR9 -Judd | No time |
| 36 | 45 | LMP2 | M | Boutsen Energy Racing | Dominik Kraihamer
Nicolas De Crem
Norbert Lenzenverger
Antoine Leclerc | Formula Le Mans-Oreca 09 | No time |
| 37 | 50 | GT1 | M | Larbre Competition | Gabriel Gardel
Patrice Goueslard
Julien Canal | Saleen S7R | No time |
| 38 | 70 | GT1 | M | Marc VDS Racing Team | Bas Leinders
Maxime Martin
Eric De Donker | Ford GT | No time |
| 39 | 78 | GT2 | D | BMW Team Schnitzer | Jörg Müller
Dirk Werner
Uwe Altzen | BMW M3 | No time |
| 40 | 87 | GT2 | M | IMSA Performance Matmut | Richard Balandras
Pascal Gibon
Christophe Bourret | Porsche 997 GT3 RSR | No time |
| 41 | 89 | GT2 | H | Hankook-Team Farnbacher | Dominik Farnbacher
Allan Simonsen | Ferrari F430 GT | No time |
