| | No | Class | T | Team | Driver | Car | Time |
| 1 | 16 | LMP1 | M | Pescarolo Sport | Jean-Christophe Boullion
Christophe Tinseau | Pescarolo-Judd | 1.33.520 |
| 2 | 13 | LMP1 | M | Speedy Racing Team Sebah | Andrea Belicchi
Nicolas Prost
Marcel Fassler | Lola B06/80
Coupé-Aston Martin | 1.34.158 |
| 3 | 11 | LMP1 | M | Team Oreca Matmut-AIM | Olivier Panis
Nicolas Lapierre | Courage-Oreca LC70-AIM | 1.34.969 |
| 4 | 007 | LMP1 | M | Aston Martin Racing | Jan Charouz
Stefan Mücke
Tomas Enge | Lola Aston Martin | 1.35.045 |
| 5 | 009 | LMP1 | M | Aston Martin Racing | Harold Primat
Darren Turner
Miguel Ramos | Lola Aston Martin | 1.35.155 |
| 6 | 23 | LMP1 | M | Strakka Racing | Peter Hardman
Nick Leventis
Danny Watts | Ginetta-Zytek 09S-Zytek | 1.35.259 |
| 7 | 14 | LMP1 | M | Kolles | Andrew Meyrick
Charles Zwolsman
Michael Krumm | Audi R10 TDI | 1.36.006 |
| 8 | 10 | LMP1 | M | Team Oreca Matmut-AIM | Stéphane Ortelli
Bruno Senna | Courage-Oreca LC70-AIM | 1.36.101 |
| 9 | 15 | LMP1 | M | Kolles | Christian Bakkerud
Christijan Albers | Audi R10 TDI | 1.36.503 |
| 10 | 12 | LMP1 | M | Signature Plus | Pierre Ragues
Frank Mailleux | Courage-Oreca LC70-Judd | 1.36.829 |
| 11 | 17 | LMP1 | M | Pescarolo Sport | Bruce Jouanny
João Barbosa | Pescarolo-Judd | 1.36.872 |
| 12 | 33 | LMP2 | M | Speedy Racing Team Sebah | Xavier Pompidou
Jonny Kane
Benjamin Leuenberger | Lola B08/80 Coupe-Judd | 1.37.032 |
| 13 | 29 | LMP2 | M | Racing Box | Filippo Francioni
Andrea Ceccato
Giacomo Piccini | Lola B08/80 Coupé-Judd | 1.37.691 |
| 14 | 25 | LMP2 | M | RML | Tommy Erdos
Mike Newton | Lola B08/80 Coupé-Mazda | 1.37.837 |
| 15 | 40 | LMP2 | D | Quifel-ASM Team | Miguel Amaral
Olivier Pla | Ginetta-Zytek 09S-Zytek | 1.37.885 |
| 16 | 30 | LMP2 | M | Racing Box | Andrea Piccini
Matteo Bobbi
Thomas Biagi | Lola B08/80 Coupé-Judd | 1.39.423 |
| 17 | 41 | LMP2 | M | G.A.C. Racing Team | Karim Oijeh
Claude-Yves Gosselin
Phillip Peter | Zytek 07S-Zytek | 1.39425 |
| 18 | 39 | LMP2 | D | Kruse Schiller Motorsport | Hideki Noda
Francesco Sini
Matthew Marsh | Lola B09/86-Mazda | 1.40.306 |
| 19 | 26 | LMP2 | D | Bruichladdich Bruneau | Pierre Bruneau
Stuart Moseley
Nigel Greensall | Radical SR9 -AER | 1.41.132 |
| 20 | 35 | LMP2 | D | Oak Racing | Matthieu Lahaye
Karim Ajlani | Pescarolo-Mazda | 1.41.251 |
| 21 | 37 | LMP2 | D | WR/Salini | Stéphane Salini
Philippe Salini
Tristan Gommendy | WR-Zytek | 1.42.376 |
| 22 | 24 | LMP2 | D | Oak Racing | Richard Hein
Jacques Nicolet | Pescarolo-Mazda | 1.42.984 |
| 23 | 55 | GT1 | M | IPB Spartak Racing | Roman Rusinov
Peter Kox | Lamborghini Murcielago R-GT | 1.44.681 |
| 24 | 38 | LMP2 | A | Pegasus Racing | Julien Schell
Philippe Thirion | Courage-Oreca LC75-AER | 1.44.694 |
| 25 | 42 | LMP2 | D | Ranieri Randaccio | Ranieri Randaccio
Raffaele Giammaria | Lucchini-Nicholson McLaren | 1.44.986 |
| 26 | 72 | GT1 | D | Luc Alphand Aventures | Luc Alphand
Patrice Goueslard
Yann Clairay | Corvette C6.R | 1.45.635 |
| 27 | 50 | GT1 | M | Larbre Competition | Fréderic Makowiecki
Patrick Bornhauser
David Smet | Saleen S7R-Ford | 1.47.623 |
| 28 | 28 | LMP2 | D | Ibanez Racing Service | José Ibanez
William Cavailhes
Frederic Da Rocha | Courage LC75 | 1.47.799 |
| 29 | 77 | GT2 | M | Team Felbermayr Proton | Richard Lietz
Marc Lieb | Porsche 997 GT3 RSR | 1.48.145 |
| 30 | 92 | GT2 | D | JMW Motorsport | Rob Bell
Gianmaria Bruni | Ferrari F430 GT | 1.48.729 |
| 31 | 51 | GT1 | D | Arc Bratislava - Kaneko Racing | Miro Konopka
Sean Edwards
Paul Daniels | Saleen S7R | 1.48.909 |
| 32 | 76 | GT2 | M | IMSA Performance Matmut | Raymond Narac
Patrick Pilet | Porsche 997 GT3 RSR | 1.48.966 |
| 33 | 84 | GT2 | M | Team Modena | Antonio Garcia
Leo Mansell | Ferrari F430 GT | 1.49.250 |
| 34 | 89 | GT2 | H | Hankook-Team Farnbacher | Allan Simonsen
Christian Montanari
Sominik Schwager | Ferrari F430 GT | 1.49.343 |
| 35 | 85 | GT2 | M | Snoras Spyker Squadron | Tom Coronel
Jarek Janis | Spyker C8 Laviolette GT2R | 1.49.386 |
| 36 | 99 | GT2 | D | JMB Racing | John Hartshorne
Yvan Lebon
Romain Ianetta | Ferrari F430 GT | 1.49.872 |
| 37 | 90 | GT2 | D | FBR | Pierre Ehret
Anthony Beltoise | Ferrari F430 GT | 1.49.938 |
| 38 | 96 | GT2 | D | Virgo Motorsport | Michael Vergers
Michael McInerney
Sean McInerney | Ferrari F430 GT | 1.50.599 |
| 39 | 43 | LMP2 | D | Q8 Oils Hache Team | Enrico Moncada
Maximo Cortez
Fabrizio Armetta | Lucchini-Judd | 1.50.821 |
| 40 | 88 | GT2 | M | Team Felbermayr Proton | Horst Felbermayr Jr
Christian Ried
Francisco Cruz Martins | Porsche 997 GT3 RSR | 1.51.138 |
| 41 | 87 | GT2 | M | Drayson Racing | Paul Drayson
Jonny Cocker | Aston Martin Vantage GT2 | 1.51.237 |
| 42 | 81 | GT2 | P | Easyrace | Maurice Basso
Roberto Plati
GianPaolo Tenchini | Ferrari F430 GT | 1.52.424 |
| 43 | 91 | GT2 | M | FBR | Gabrio Rosa
Giacomo Petrobelli
Andrea Montermini | Ferrari F430 GT | 1.52.569 |
