| Pos | No. | Class | T | Team | Driver | Car | Time |
| 1 | 2 | LMP1 | M | Audi Sport Team Joest | Marcel Fässler
André Lotterer
Benoit Treluyer | Audi R18 TDI | 3:25.738 |
| 2 | 1 | LMP1 | M | Audi Sport Team Joest | Timo Bernhard
Romain Dumas
Mike Rockenfeller | Audi R18 TDI | 3:25.799 |
| 3 | 9 | LMP1 | M | Team Peugeot Total | Sébastien Bourdais
Simon Pagenaud
Pedro Lamy | Peugeot 908 | 3:26.010 |
| 4 | 8 | LMP1 | M | Peugeot Sport Total | Stéphane Sarrazin
Franck Montagny
Nicolas Minassian | Peugeot 908 | 3:26.156 |
| 5 | 3 | LMP1 | M | Audi Sport North America | Tom Kristensen
Rinaldo Capello
Allan McNish | Audi R18 TDI | 3:26.165 |
| 6 | 7 | LMP1 | M | Peugeot Sport Total | Anthony Davidson
Marc Gené
Alex Wurz | Peugeot 908 | 3:26.272 |
| 7 | 10 | LMP1 | M | Team Oreca Matmut | Nicolas Lapierre
Loïc Duval
Olivier Panis | Peugeot 908 HDi FAP | 3:30.084 |
| 8 | 12 | LMP1 | M | Rebellion Racing | Nicolas Prost
Neel Jani
Jeroen Bleekemolen | Lola B10/60 Coupé Toyota | 3:32.883 |
| 9 | 16 | LMP1 | M | Pescarolo Team | Emmanuel Collard
Christophe Tinseau
Julien Jousse | Pescarolo Judd | 3:33.066 |
| 10 | 13 | LMP1 | M | Rebellion Racing | Andrea Belicchi
Jean Christophe Boullion
Guy Smith | Lola B10/60 Coupé Toyota | 3:34.573 |
| 11 | 15 | LMP1 | D | OAK Racing | Guillaume Moreau
Pierre Ragues
Tiago Monteiro | OAK Pescarolo Judd | 3:34.933 |
| 12 | 22 | LMP1 | M | Kronos Racing | Vanina Ickx
Maxime Martin
Bas Leinders | Lola Aston Martin | 3:36.551 |
| 13 | 20 | LMP1 | D | Quifel-ASM Team | Miguel Amaral
Olivier Pla
Warren Hughes | Zytek 09 SC | 3:37.393 |
| 14 | 26 | LMP2 | D | Signatech Nissan | Soheil Ayari
Franck Mailleux
Lucas Ordonez | Oreca 03 Nissan | 3:41.458 |
| 15 | 24 | LMP1 | D | OAK Racing | Richard Hein
Jacques Nicolet
Jean-François Yvon | OAK Pescarolo Judd | 3:41.908 |
| 16 | 42 | LMP2 | M | Strakka Racing | Nick Leventis
Danny Watts
Jonny Kane | HPD ARX 01 d | 3:42.615 |
| 17 | 48 | LMP2 | M | Team Oreca Matmut | Alexandre Premat
David Hallyday
Dominik Kraihamer | Oreca 03 Nissan | 3:43.098 |
| 18 | 39 | LMP2 | M | Pecom Racing | Luis Perez Companc
Matias Russo
Pierre Kaffer | Lola B11/40 Judd-BMW | 3:43.223 |
| 19 | 49 | LMP2 | D | OAK Racing | Shinji Nakano
Nicolas de Crem
Jan Charouz | OAK Pescarolo BMW | 3:43.479 |
| 20 | 41 | LMP2 | D | Greaves Motorsport | Karim Ojjeh
Tom Kimber-Smith
Olivier Lombard | Zytek Nissan | 3:43.802 |
| 21 | 40 | LMP2 | D | Race Performance | Michel Frey
Ralph Meichtry
Marc Rostan | Oreca 03 Judd-BMW | 3:44.294 |
| 22 | 007 | LMP1 | M | Aston Martin Racing | Stefan Mücke
Darren Turner
Christian Klien | Aston Martin AMR-One | 3:45.918 |
| 23 | 36 | LMP2 | D | RML | Mike Newton
Tommy Erdos
Ben Collins | HPD ARX-01d | 3:47.308 |
| 24 | 5 | LMP1 | M | Hope Racing | Steve Zacchia
Jan Lammers
Casper Elgaard | Oreca Swiss Hy Tech-Hybrid | 3:47.691 |
| 25 | 009 | LMP1 | M | Aston Martin Racing | Harold Primat
Adrian Fernandez
Andy Meyrick | Aston Martin AMR-One | 3:48.355 |
| 26 | 44 | LMP2 | D | Extreme Limite AM Paris | Fabien Rosier
Philippe Haezebrouck
Jean-René de Fournoux | Norma M200P Judd BMW | 3:48.420 |
| 27 | 35 | LMP2 | D | OAK Racing | Andrea Barlesi
Frédéric Da Rocha
Patrice Lafargue | OAK Pescarol Judd-BMW | 3:48.665 |
| 28 | 33 | LMP2 | M | Level 5 Motorsports | Scott Tucker
Christophe Bouchut
João Barbosa | Lola Coupé HPD | 3:48.863 |
| 29 | 55 | GTE P | D | BMW Motorsport | Augusto Farfus
Jörg Muller
Dirk Werner | BMW M3 GT | 3:57.952 |
| 30 | 51 | GTE P | M | AF Corse | Giancarlo Fisichella
Gianmaria Bruni
Toni Vilander | Ferrari 458 Italia | 3:58.040 |
| 31 | 56 | GTE P | D | BMW Motorsport | Andy Priaulx
Dirk Muller
Joey Hand | BMW M3 GT | 3:58.426 |
| 32 | 89 | GTE P | H | Hankook-Team Farnbacher | Dominik Farnbacher
Allan Simonsen
Leh Keen | Ferrari 458 Italia | 3:59.519 |
| 33 | 74 | GTE P | M | Corvette Racing | Oliver Gavin
Jan Magnussen
Richard Westbrook | Chevrolet Corvette C6 ZR1 | 3:59.519 |
| 34 | 73 | GTE P | M | Corvette Racing | Olivier Beretta
Tommy Milner
Antonio Garcia | Chevrolet Corvette C6 ZR1 | 3:59.633 |
| 35 | 77 | GTE P | M | Team Felbermayr-Proton | Marc Lieb
Richard Lietz
Wolf Henzler | Porsche 911 RSR (997) | 3:59.662 |
| 36 | 59 | GTE P | M | Luxury Racing | Stéphane Ortelli
Frédéric Makowiecki
Jaime Melo | Ferrari 458 Italia | 3:59.901 |
| 37 | 75 | GTE P | M | ProSpeed Competition | Marc Goossens
Marco Holzer
Jaap van Lagen | Porsche 911 RSR (997) | 3:59.962 |
| 38 | 79 | GTE P | D | Jota | Sam Hancock
Simon Dolan
Chris Buncombe | Aston Martin Vantage | 4:00.747 |
| 39 | 66 | GTE P | D | JMW Motorsport | Rob Bell
Tim Sugden
Xavier Maassen | Ferrari 458 Italia | 4:00.890 |
| 40 | 80 | GTE P | M | Flying Lizard Motorsports | Jörg Bergmeister
Patrick Long
Lucas Luhr | Porsche 911 RSR (997) | 4:01.024 |
| 41 | 58 | GTE P | M | Luxury Racing | Anthony Beltoise
Jean-Denis Deletraz
François Jakubowski | Ferrari 458 Italia | 4:01.176 |
| 42 | 61 | GTE A | M | AF Corse | Piergiuseppe Perazzini
Marco Cioci
Sean Paul Breslin | Ferrari F430 GT2 | 4:01.282 |
| 43 | 88 | GTE P | M | Team Felbermayr-Proton | Nick Tandy
Abdulaziz Al Faisal
Bryce Miller | Porsche 911 RSR (997) | 4:01.752 |
| 44 | 71 | GTE P | M | AF Corse | Robert Kauffman
Michael Waltrip
Rui Aguas | Ferrari 458 Italia | 4:02.216 |
| 45 | 76 | GTE P | M | IMSA Performance Matmut | Raymond Narac
Patrick Pilet
Nicolas Armindo | Porsche 911 RSR (997) | 4:02.548 |
| 46 | 63 | GTE A | M | Proton Competition | Horst Felbermayr Jr
Horst Felbermayr Snr
Christian Reid | Porsche 911 RSR (997) | 4:03.532 |
| 47 | 81 | GTE A | M | Flying Lizard Motorsports | Seth Neiman
Darren Law
Spencer Pumpelly | Porsche 911 RSR (997) | 4:03.648 |
| 48 | 70 | GTE A | M | Larbre Competition | Christophe Bourret
Pascal Gibon
Jean-Philippe Belloc | Porsche 911 RSR (997) | 4:03.918 |
| 49 | 83 | GTE A | M | JMB Racing | Manuel Rodrigues
Jean Marc Menahem
Nicolas Marroc | Ferrari F430 GT2 | 4:04.640 |
| 50 | 60 | GTE A | D | Gulf AMR Middle East | Fabien Giroix
Michael Wainwright
Roald Goethe | Aston Martin Vantage | 4:04.825 |
| 51 | 57 | GTE A | D | Krohn Racing | Tracy Krohn
Nic Jönsson
Michele Rugolo | Ferrari F430 GT2 | 4:05.211 |
| 52 | 50 | GTE A | M | Larbre Competition | Patrick Bornhauser
Julien Canal
Gabriele Gardel | Chevrolet Corvette C6 ZR1 | 4:05.955 |
| 53 | 62 | GTE A | M | CRS Racing | Pierre Ehret
Roger Wills
Shaun Lynn | Ferrari F430 GT2 | 4:07.236 |
| 54 | 65 | GTE P | M | Lotus Jetalliance | Jonathan Hirschi
James Rossitter
Johnny Mowlem | Lotus Evora | 4:07.465 |
| 55 | 68 | GTE A | M | Robertson Racing | David Robertson
Andrea Robertson
David Murry | Doran Ford GT | 4:08.208 |
| 56 | 64 | GTE P | M | Lotus Jetalliance | Oskar Slingerland
Martin Rich
John Hartshorne | Lotus Evora |  |
