| | No. | Class | Team | Driver | Car | Time |
| 1 | 7 | LMP1 | Team Peugeot Total | Marc Gene Nicolas Minassian | Peugeot 908 HDi-FAP | 1:33.113 |
| 2 | 8 | LMP1 | Team Peugeot Total | Pedro Lamy Stephane Sarrazin | Peugeot 908 HDi-FAP | 1:33.648 |
| 3 | 2 | LMP1 | Audi Sport Team Joest | Alexandre Premat Mike Rockenfeller | Audi R10 TDI | 1:34.770 |
| 4 | 1 | LMP1 | Audi Sport Team Joest | Allan McNish Rinaldo Capello | Audi R10 TDI | 1:34.953 |
| 5 | 10 | LMP1 | Charouz Racing System | Stefan Mucke Jan Charouz | Lola B06/80-Aston Martin | 1:35.346 |
| 6 | 6 | LMP1 | Team Oreca Matmut | Olivier Panis Nicolas Lapierre | Courage-Oreca LC70-Judd | 1:36.121 |
| 7 | 5 | LMP1 | Team Oreca Matmut | Stephane Ortelli Soheil Ayari | Courage-Oreca LC70-Judd | 1:36.547 |
| 8 | 16 | LMP1 | Pescarolo Sport | Emmanuel Collard Jean-Christophe Boullion | Pescarolo-Judd | 1:37.516 |
| 9 | 20 | LMP1 | Epsilon-Euskadi | Angel Burgueno Miguel Angel de Castro | Epsilon Euskadi ee1-Judd | 1:37.761 |
| 10 | 34 | LMP2 | Van Merksteijn Motorsport | Peter van Merksteijn Jos Verstappen | Porsche RS-Spyder | 1:37.798 |
| 11 | 14 | LMP1 | Creation AIM | Jamie Campbell-Walter Stuart Hall | Creation CA07-AIM | 1:38.193 |
| 12 | 17 | LMP1 | Pescarolo Sport | Harold Primat Christophe Tinseau | Pescarolo-Judd | 1:38.772 |
| 13 | 33 | LMP2 | Speedy Racing Team Sebah | Andrea Belicchi Steve Zacchia Xavier Pompidou | Lola B08/80 Coupe-Judd | 1:39.016 |
| 14 | 31 | LMP2 | Team Essex | John Nielsen Casper Elgaard | Porsche RS-Spyder | 1:39.535 |
| 15 | 15 | LMP1 | Creation AIM | Robbie Kerr Bruce Jouanny | Creation CA07-AIM | 1:39.777 |
| 16 | 32 | LMP2 | Barazi-Epsilon | Juan Barazi Michael Vergers Fernando Rees | Zytek 07S-Zytek | 1:40.072 |
| 17 | 27 | LMP2 | Horag Racing | Fredy Lienhard Didier Theys Jan Lammers | Porsche RS-Spyder | 1:40.379 |
| 18 | 18 | LMP1 | Rollcentre Racing | Duncan Tappey Vanina Ickx Martin Short | Pescarolo-Judd | 1:41.105 |
| 19 | 46 | LMP2 | Embassy Racing | Jonny Kane Joey Foster | WF01-Zytek | 1:41.554 |
| 20 | 35 | LMP2 | Saulnier Racing | Pierre Ragues Matthieu Lahaye | Pescarolo-Judd | 1:42.086 |
| 21 | 4 | LMP1 | Saulnier Racing | Jacques Nicolet Marc Faggionato Richard Hein | Pescarolo-Judd | 1:42.104 |
| 22 | 41 | LMP2 | Trading Performance | Karim Ojjeh Claude-Yves Gosselin Julien Schroyen | Zytek 07S-Zytek | 1:42.334 |
| 23 | 40 | LMP2 | Quifel-ASM Team | Miguel Amaral Olivier Pla | Lola B050/40-AER | 1:42.715 |
| 24 | 25 | LMP2 | RML | Tommy Erdos Mike Newton | MG Lola EX265-MG | 1:42.894 |
| 25 | 45 | LMP2 | Embassy Racing | Warren Hughes Mario Haberfeld | WF01-Zytek | 1:43.047 |
| 26 | 26 | LMP2 | Bruichladdich Radical | Marc Rostan Jens Petersen Jan-Dirk Lueders | Radical SR9 -AER | 1:43.953 |
| 27 | 30 | LMP2 | Racing Box | Marco Didaio Filippo Francioni | Lucchini-Judd | 1:44.858 |
| 28 | 44 | LMP2 | Kruse Schiller Motorsport | Jean de Pourtales Hideki Noda | Lola B05/40-Mazda | 1:45.296 |
| 29 | 59 | GT1 | Team Modena | Antonio Garcia Tomas Enge | Aston Martin DBR9 | 1:46.443 |
| 30 | 73 | GT1 | Luc Alphand Aventures | Sebastien Dumez Jean-Luc Blanchemain Roland Berville | Corvette C6.R | 1:46.688 |
| 31 | 72 | GT1 | Luc Alphand Aventures | Olivier Beretta Guillaume Moreau Patrice Goueslard | Corvette C6.R | 1:47.033 |
| 32 | 55 | GT1 | IPB Spartak Racing | Roman Rusinov Peter Kox | Lamborghini Murcielago R-GT | 1:47.625 |
| 33 | 77 | GT2 | Team Felbermayr Proton | Marc Lieb Alex Davison | Porsche 997 GT3 RSR | 1:49.828 |
| 34 | 96 | GT2 | Virgo Motorsport | Rob Bell Gianmaria Bruni | Ferrari F430 GT | 1:50.805 |
| 35 | 76 | GT2 | IMSA Performance Matmut | Raymond Narac Richard Lietz | Porsche 997 GT3 RSR | 1:51.547 |
| 36 | 91 | GT2 | Farnbacher Racing | Lars Erik Nielsen Allan Simonsen Richard Westbrook | Porsche 997 GT3 RSR | 1:51.813 |
| 37 | 37 | LMP2 | WR/Salini | Stephane Salini Philippe Salini Patrice Roussel | WR-Zytek | 1:52.043 |
| 38 | 95 | GT2 | James Watt Automotive | Markus Palttala Paul Daniels | Porsche 997 GT3 RSR | 1:52.502 |
| 39 | 85 | GT2 | Snoras Spyker Squadron | Peter Dumbreck Ralf Kelleners Alexei Vasiliev | Spyker C8 Laviolette GT2R | 1:52.546 |
| 40 | 75 | GT2 | IMSA Performance Matmut | Richard Balandras Michel Lecourt Jean-Philippe Belloc | Porsche 997 GT3 RSR | 1:52.822 |
| 41 | 99 | GT2 | JMB Racing | Stephane Daoudi Ben Aucott | Ferrari F430 GT | 1:52.906 |
| 42 | 94 | GT2 | Speedy Racing Team | Andrea Chiesa Benjamin Leuenberger | Spyker C8 Laviolette GT2R | 1:53.783 |
| 43 | 98 | GT2 | JMB Racing | Peter Kutemann Maurice Basso | Ferrari F430 GT | 1:58.504 |
| 44 | 90 | GT2 | Farnbacher Racing | Pierre Ehret Pierre Kaffer | Ferrari F430 GT | No Time |
| 45 | 88 | GT2 | Team Felbermayr Proton | Horst Felbermayr Jr Christian Ried Horst Felbermayr Sr | Porsche 997 GT3 RSR | No Time |
| 46 | 21 | LMP1 | Epsilon-Euskadi (withdrawn) | TBA | Epsilon Euskadi ee1-Judd | No Time |
| 47 | 12 | LMP1 | Charouz Racing System (withdrawn) | Greg Pickett Klaus Graf | Lola B07/17 Judd | No Time |
| 48 | 93 | GT2 | James Watt Automotive (withdrawn) | Alan van der Merwe TBA | Aston Martin Vantage V8 | No Time |
| 49 | 50 | GT1 | Larbre Competition (withdrawn) | Frederic Makowiecki Patrick Bornhauser Christophe Bouchut | Saleen S7R-Ford | No Time |