| Pos | No. | Class | T | Team | Driver | Car | Time |
| 1 | 1 | LMP1 | M | Audi Sport Team Joest | Timo Bernhard
Romain Dumas
Mike Rockenfeller | Audi R18 TDI | 3:27.900 |
| 2 | 2 | LMP1 | M | Audi Sport Team Joest | Marcel Fässler
André Lotterer
Benoit Treluyer | Audi R18 TDI | 3:28.503 |
| 3 | 3 | LMP1 | M | Audi Sport North America | Tom Kristensen
Rinaldo Capello
Allan McNish
Marco Bonanomi | Audi R18 TDI | 3:30.382 |
| 4 | 8 | LMP1 | M | Peugeot Sport Total | Franck Montagny
Stéphane Sarrazin
Nicolas Minassian | Peugeot 908 | 3:30.516 |
| 5 | 7 | LMP1 | M | Peugeot Sport Total | Alexander Wurz
Marc Gené
Anthony Davidson | Peugeot 908 | 3:32.549 |
| 6 | 9 | LMP1 | M | Team Peugeot Total | Sébastien Bourdais
Simon Pagenaud
Pedro Lamy | Peugeot 908 | 3:32.578 |
| 7 | 10 | LMP1 | M | Team Oreca Matmut | Nicolas Lapierre
Loïc Duval | Peugeot 908 HDi FAP | 3:34.317 |
| 8 | 16 | LMP1 | M | Pescarolo Team | Emmanuel Collard
Christophe Tinseau
Julien Jousse | Pescarolo Judd | 3:37.640 |
| 9 | 12 | LMP1 | M | Rebellion Racing | Nicolas Prost
Neel Jani
Jeroen Bleekemolen | Lola B10/60 Toyota | 3:38.537 |
| 10 | 13 | LMP1 | M | Rebellion Racing | Andrea Belicchi
Jean Christophe Boullion
Guy Smith | Lola B10/60 Toyota | 3:40.264 |
| 11 | 15 | LMP1 | D | OAK Racing | Matthieu Lahaye
Guillaume Moreau
Pierre Ragues | OAK Pescarolo Judd | 3:41.520 |
| 12 | 41 | LMP2 | D | Greaves Motorsport | Karim Ojjeh
Gary Chalandon
Tom Kimber-Smith
Alex Brundle | Zytek Nissan | 3:43.601 |
| 13 | 26 | LMP2 | D | Signatech Nissan | Franck Mailleux
Lucas Ordonnez
Soheil Ayari | Oreca 03 Nissan | 3:44.424 |
| 14 | 22 | LMP1 | M | Kronos Racing | Vanina Ickx
Maxime Martin
Bas Leinders | Lola Aston Martin | 3:45.555 |
| 15 | 48 | LMP2 | M | Team Oreca Matmut | David Halliday
Alexandre Primat
Dominik Kraihamer | Oreca 03 Nissan | 3:45.909 |
| 16 | 39 | LMP2 | M | Pecom Racing | Luis Perez Companc
Matias Russo
Pierre Kaffer | Lola B11/40 Judd-BMW | 3:46.097 |
| 17 | 24 | LMP1 | D | OAK Racing | Jacques Nicolet
Richard Hein
Jean-François Yvon | OAK Pescarolo Judd | 3:47.892 |
| 18 | 46 | LMP2 | M | TDS Racing | Pierre Thiriet
Mathias Beche
Jody Firth | Oreca 03 Nissan | 3:49.723 |
| 19 | 34 | LMP2 | M | Level 5 Motorsports | Scott Tucker
Christophe Bouchut
Joao Barbosa | Lola Coupé HPD | 3:50.805 |
| 20 | 23 | LMP1 | D | MIK Corse | Maximo Cortes
Ferdinando Geri
Giacomo Piccini
Andrea Piccini | Zytek 09H Hybrid | 3:51.527 |
| 21 | 007 | LMP1 | M | Aston Martin Racing | Stefan Mücke
Darren Turner
Christian Klien | Aston Martin AMR-One | 3:51.568 |
| 22 | 40 | LMP2 | D | Race Performance | Michel Frey
Ralph Meichtry
Marc Rostan | Oreca 03 Judd-BMW | 3:53.045 |
| 23 | 36 | LMP2 | D | RML | Mike Newton
Tommy Erdos
Ben Collins | HPD ARX-01d | 3:56.647 |
| 24 | 93 | FLM | M | Genoa Racing | Jens Petersen
Elton Julian
Christian Zugel | Oreca | 3:57.233 |
| 25 | 91 | FLM | M | Hope Racing | Luca Moro
Zhang Shan Qi
Nicolas Marroc | Oreca | 3:58.369 |
| 26 | 44 | LMP2 | D | Extreme Limite AM Paris | Fabien Rosier
Jean-René de Fournoux
Philippe Haezebrouck | Norma M200P Judd BMW | 4:00.561 |
| 27 | 89 | GTE P | H | Hankook-Team Farnbacher | Dominik Farnbacher
Allan Simonsen | Ferrari 458 Italia | 4:01.495 |
| 28 | 51 | GTE P | M | AF Corse | Giancarlo Fisichella
Gianmaria Bruni | Ferrari 458 Italia | 4:02.477 |
| 29 | 99 | FLM | M | JMB Racing | John Hartshorne
Philippe Mondolot
Olivier Lombard | Oreca | 4:03.072 |
| 30 | 56 | GTE P | D | BMW Motorsport | Andy Priaulx
Dirk Muller
Joey Hand | BMW M3 GT | 4:04.045 |
| 31 | 77 | GTE P | M | Team Felbermayr-Proton | Marc Lieb
Richard Lietz
Christian Reid | Porsche 997 GT3 RSR | 4:04.122 |
| 32 | 79 | GTE P | D | Jota | Sam Hancock
Simon Dolan
Chris Buncombe | Aston Martin Vantage | 4:04.594 |
| 33 | 50 | GTE A | M | Larbre Competition | Tommy Milner
Oliver Gavin
Olivier Beretta | Chevrolet Corvette C6-ZR1 | 4:04.853 |
| 34 | 59 | GTE P | M | Luxury Racing | Stéphane Ortelli
Frédéric Makowiecki
Jean-Denis Deletraz | Ferrari 458 Italia | 4:04.997 |
| 35 | 55 | GTE P | D | BMW Motorsport | Augusto Farfus
Jorg Muller
Dirk Werner | BMW M3 GT | 4:05.314 |
| 36 | 76 | GTE P | M | IMSA Performance Matmut | Raymond Narac
Patrick Pilet
Nicolas Armindo | Porsche 997 GT3 RSR | 4:06.056 |
| 37 | 69 | GTE P | M | Robertson Racing | David Murry
Anthony Lazzaro
Colin Braun | Doran Ford GT | 4:06.748 |
| 38 | 58 | GTE P | M | Luxury Racing | Anthony Beltoise
François Jakubowski | Ferrari 458 Italia | 4:07.160 |
| 39 | 61 | GTE A | M | AF Corse | Piergiuseppe Perazzini
Marco Cioci
Sean Paul Breslin | Ferrari F430 GT2 | 4:07.524 |
| 40 | 88 | GTE P | M | Team Felbermayr-Proton | Abdulaziz Bin Turki Al Faisal
Bryce Miller
Nick Tandy
Spencer Pumpelly | Porsche 997 GT3 RSR | 4:08.861 |
| 41 | 71 | GTE P | M | AF Corse | Robert Kauffman
Michael Waltrip
Rui Aguas | Ferrari F430 GT2 | 4:09.351 |
| 42 | 70 | GTE A | M | Larbre Competition | Christophe Bourret
Pascal Gibon
Jean-Philippe Belloc | Porsche 997 GT3 RSR | 4:09.456 |
| 43 | 33 | LMP2 | M | Level 5 Motorsports | Scott Tucker
Christophe Bouchut
Joao Barbosa | Lola Coupé HPD | 4:10.063 |
| 44 | 86 | GTE P | M | Young Driver AMR | Tomas Enge
Alex Muller | Aston Martin Vantage | 4:10.859 |
| 45 | 62 | GTE A | M | CRS Racing | Pierre Ehret
Shaun Lynn
Roger Wills
Andrew Kirkaldy | Ferrari F430 GT2 | 4:11.240 |
| 46 | 65 | GTE P | M | Lotus Jetalliance | Jonathan Hirschi
Johnny Mowlem
James Rossitter | Lotus Evora | 4:11.250 |
| 47 | 83 | GTE A | M | JMB Racing | Manuel Rodrigues
Tristan Gommendy
Jean Marc Menahem
Nicolas Misslin | Ferrari F430 GT2 | 4:11.476 |
| 48 | 68 | GTE A | M | Robertson Racing | David Robertson
Andrea Robertson
Boris Said | Doran Ford GT | 4:12.971 |
| 49 | 52 | GTE A | M | AF Corse | Michele Rugolo | Ferrari F430 | 4:13.921 |
| 50 | 35 | LMP2 | D | OAK Racing | Frédéric Da Rocha
Patrice Lafargue
Andrea Barlesi | OAK Pescarol Judd-BMW | 4:13.951 |
| 51 | 60 | GTE A | D | Gulf AMR Middle East | Fabien Giroix
Roald Goethe
Michael Wainwright | Aston Martin Vantage | 4:15.020 |
| 52 | 64 | GTE P | M | Lotus Jetalliance | Lukas Lichtner-Hoyer
Martin Rich
Oskar Slingerland | Lotus Evora | 4:20.925 |
| 53 | 009 | LMP1 | M | Aston Martin Racing | Harold Primat
Adrian Fernandez
Andy Meyrick | Aston Martin AMR-One | No Time |
| 54 | 5 | LMP1 | M | Hope Racing | Steve Zacchia
Nicolas Marroc | Oreca Swiss
Hy Tech-Hybrid | No Time |
