| | No | Class | T | Team | Driver | Car | Time |
| 1 | 10 | LMP1 | M | Team Oreca Matmut - AIM | Olivier Panis
Nicolas Lapierre | Courage-Oreca LC70-AIM | 1:32.798 |
| 2 | 007 | LMP1 | M | Aston Martin Racing | Jan Charouz
Stefan Mücke
Tomas Enge | Lola Aston Martin | 1:33.714 |
| 3 | 009 | LMP1 | M | Aston Martin Racing | Harold Primat
Darren Turner | Lola Aston Martin | 1:34.618 |
| 4 | 13 | LMP1 | M | Speedy Racing Team Sebah | Andrea Belicchi
Nicolas Prost
Marcel Fassler | Lola B06/80
Coupé-Aston Martin | 1:34.654 |
| 5 | 5 | LMP1 | M | Team LNT | Lawrence Tomlinson
Nigel Mansell
Greg Mansell | Ginetta-Zytek GZ09S-Zytek | 1:35.296 |
| 6 | 14 | LMP1 | M | Kolles | Andrew Meyrick
Charles Zwolsman
Narain Karthikeyan | Audi R10 TDI | 1:35.522 |
| 7 | 008 | LMP1 | M | AMR Eastern Europe | Miguel Ramos
Stuart Hall
Chris Buncombe | Lola Aston Martin | 1:36.014 |
| 8 | 40 | LMP2 | D | Quifel-ASM Team | Miguel Amaral
Olivier Pla | Ginetta-Zytek 09S-Zytek | 1:36.092 |
| 9 | 12 | LMP1 | M | Signature Plus | Pierre Ragues
Frank Mailleux | Courage-Oreca LC70-Judd | 1:36.292 |
| 10 | 33 | LMP2 | M | Speedy Racing Team Sebah | Xavier Pompidou
Jonny Kane
Benjamin Leuenberger | Lola B08/80 Coupe-Judd | 1:37.128 |
| 11 | 25 | LMP2 | M | RML | Tommy Erdos
Mike Newton | Lola B08/80 Coupé-Mazda | 1:37.280 |
| 12 | 41 | LMP2 | M | G.A.C. Racing Team | Karim Oijeh
Claude-Yves Gosselin
Philipp Peter | Zytek 07S-Zytek | 1:38.210 |
| 13 | 45 | LMP2 | D | Team WFR | Warren Hughes
Jody Firth
Darren Manning | WF01-Zytek | 1:38.810 |
| 14 | 37 | LMP2 | D | WR/Salini | Stéphane Salini
Philippe Salini
Tristan Gommendy | WR-Zytek | 1:39.096 |
| 15 | 35 | LMP2 | D | Oak Racing | Matthieu Lahaye
Karim Ajlani | Pescarolo-Mazda | 1:39.396 |
| 16 | 24 | LMP2 | D | Oak Racing | Richard Hein
Jacques Nicolet | Pescarolo-Mazda | 1:40.116 |
| 17 | 28 | LMP2 | D | Ibanez Racing Service | José Ibanez
William Cavailhes
Frederic Da Rocha | Courage LC75 | 1:41.922 |
| 18 | 26 | LMP2 | D | Bruichladdich Bruneau | Pierre Bruneau
Francesco Sini
Tim Greaves | Radical SR9 -AER | 1:42.340 |
| 19 | 43 | LMP2 | D | Q8 Oils Hache Team | Maximo Cortez
Carmen Jorda
Alfonso "Fonsi" Nieto | Lucchini-Judd | 1:43.470 |
| 20 | 38 | LMP2 | A | Pegasus Racing | Julien Schell
Philippe Thirion
Jean-Christophe Metz | Courage-Oreca LC75-AER | 1:44.486 |
| 21 | 50 | GT1 | M | Larbre Competition | Roland Berville
Sébastien Dumez
Laurent Groppi | Saleen S7R-Ford | 1:45.714 |
| 22 | 60 | GT1 | M | Gigawave Motorsport | Ryan Sharp
Peter Kox | Aston Martin DBR9 | 1:45.796 |
| 23 | 72 | GT1 | D | Luc Alphand Aventures | Julien Jousse
Patrice Goueslard
Yann Clairay | Corvette C6.R | 1:45.848 |
| 24 | 77 | GT2 | M | Team Felbermayr Proton | Richard Lietz
Marc Lieb
Horst Felbermayr Sr | Porsche 997 GT3 RSR | 1:48.638 |
| 25 | 92 | GT2 | D | JMW Motorsport | Rob Bell
Gianmaria Bruni | Ferrari F430 GT | 1:48.830 |
| 26 | 76 | GT2 | M | IMSA Performance Matmut | Raymond Narac
Patrick Pilet | Porsche 997 GT3 RSR | 1:48.984 |
| 27 | 84 | GT2 | M | Team Modena | Antonio Garcia
Leo Mansell
Jaime Melo | Ferrari F430 GT | 1:49.358 |
| 28 | 89 | GT2 | H | Hankook-Team Farnbacher | Christian Montanari
Pierre Kaffer | Ferrari F430 GT | 1:49.570 |
| 29 | 87 | GT2 | M | Drayson Racing | Paul Drayson
Jonny Cocker | Aston Martin Vantage GT2 | 1:49.594 |
| 30 | 91 | GT2 | D | FBR | Andrea Montermini
Giacomo Ricci
Gabrio Rosa | Ferrari F430 GT | 1:49.612 |
| 31 | 90 | GT2 | D | FBR | Pierre Ehret
Dominik Farnbacher
Anthony Beltoise | Ferrari F430 GT | 1:50.062 |
| 32 | 85 | GT2 | M | Snoras Spyker Squadron | Tom Coronel
Jarek Janis | Spyker C8 Laviolette GT2R | 1:50.342 |
| 33 | 78 | GT2 | M | Advanced Engineering | Matt Griffin
Peter Bamford | Ferrari F430 GT | 1:50.710 |
| 34 | 99 | GT2 | D | JMB Racing | John Hartshorne
Peter Kutemann
Stephane Daoudi | Ferrari F430 GT | 1:51.126 |
| 35 | 88 | GT2 | M | Team Felbermayr Proton | Horst Felbermayr Jr
Christian Ried
Francisco Cruz Martins | Porsche 997 GT3 RSR | 1:52.176 |
| 36 | 81 | GT2 | P | Easyrace | Maurice Basso
Roberto Plati
GianPaolo Tenchini | Ferrari F430 GT | 1:52.630 |
| 37 | 95 | GT2 | D | James Watt Automotive | Markus Paltalla
Paul Daniels
Martin Rich | Porsche 997 GT3 RSR | 1:52.920 |
| 38 | 16 | LMP1 | M | Pescarolo Sport | Jean-Christophe Boullion
Christophe Tinseau | Pescarolo-Judd | 5:31.444 |
| 39 | 15 | LMP1 | M | Kolles | Christian Bakkerud
Christijan Albers
Giorgio Mondini | Audi R10 TDI | 5:59.292 |
| 40 | 23 | LMP1 | M | Strakka Racing | Nick Leventis
Danny Watts | Ginetta-Zytek GZ09S-Zytek | No Time |
