| | No | Class | T | Team | Driver | Car | Time |
| 1 | 20 | LMP1 | D | Quifel - ASM Team | Miguel Amaral
Olivier Pla | Zytek 09SC | 1:49.189 |
| 2 | 16 | LMP1 | M | Pescarolo Sport | Emmanuel Collard
Christophe Tinseau
Julien Jousse | Pescarolo - Judd | 1:49.416 |
| 3 | 40 | LMP2 | D | Race Performance | Michel Frey
Ralph Meichtry | Oreca 03-Judd | 1:52.282 |
| 4 | 44 | LMP2 | D | Extreme Limite AM Paris | Fabien Rosier
Jean-Pierre Luco
Maurice Basso | Norma M200P-Judd | 1:53.374 |
| 5 | 39 | LMP2 | M | Pecom Racing | Luis Perez Companc
Matias Russo
Pierre Kaffer | Lola B11/40-Judd | 1:54.098 |
| 6 | 43 | LMP2 | D | RLR Motorsport | Barry Gates
Rob Garofall
Simon Phillips | MG Lola EX265-Judd | 1:54.848 |
| 7 | 36 | LMP2 | D | RML | Tommy Erdos
Mike Newton
Ben Collins | Honda ARX-01d | 1:55.169 |
| 8 | 91 | FLM | M | Hope Racing | Michael Tinguely
Luca Moro | Formula Le Mans-Oreca - 09 | 1:57.184 |
| 9 | 92 | FLM | M | Neil Garner Motorsport | John Hartshorne
Steave Keating
Phil Keen | Formula Le Mans-Oreca - 09 | 1:58.011 |
| 10 | 99 | FLM | M | JMB Motorsport | Manuel Rodrigues
Dino Lunardi
Jean Marc Menahem | Formula Le Mans-Oreca - 09 | 1:58.385 |
| 11 | 95 | FLM | M | Pegasus Racing | Mirco Schultis
Patrick Simon | Formula Le Mans-Oreca - 09 | 1:59.331 |
| 12 | 76 | GTP | M | IMSA Performance Matmut | Patrick Pilet
Wolf Henzler | Porsche 911 RSR (997) | 2:00.987 |
| 13 | 89 | GTP | H | Hankook-Team Farnbacher | Dominik Farnbacher
Allan Simonsen | Ferrari F430 | 2:01.048 |
| 14 | 67 | GTA | M | IMSA Performance Matmut | Raymond Narac
Nicolas Armindo | Porsche 911 RSR (997) | 2:01.158 |
| 15 | 79 | GTP | D | Jota | Sam Hancock
Simon Dolan | Aston Martin Vantage | 2:01.238 |
| 16 | 77 | GTP | M | Team Felbermayr Proton | Marc Lieb
Richard Lietz | Porsche 911 RSR (997) | 2:01.369 |
| 17 | 51 | GTP | M | AF Corse | Giancarlo Fisichella
Gianmaria Bruni | Ferrari F458 Italia | 2:01.617 |
| 18 | 61 | GTA | M | AF Corse | Piergiuseppe Perazzini
Marco Cioci
Stéphane Lemeret | Ferrari F430 | 2:01.818 |
| 19 | 82 | GTA | M | CRS Racing | Klaas Hummel
Adam Christidoulou
Phil Quaife | Ferrari F430 | 2:02.134 |
| 20 | 75 | GTP | M | Prospeed Competition | Marco Holzer
Marc Goossens | Porsche 911 RSR (997) | 2:02.530 |
| 21 | 70 | GTA | D | Kessel Racing | Michal Bromiszewski
Philipp Peter | Ferrari F458 Italia | 2:02.916 |
| 22 | 72 | GTA | M | AF Corse | Robert Kauffman
Michael Waltrip
Rui Aguas | Ferrari F430 | 2:03.671 |
| 23 | 83 | GTA | M | JMB Motorsport | Nicolas Missilin
Steve Quick
Khaled Al Qubaisi | Ferrari F430 | 2:06.606 |
| 24 | 12 | LMP1 | M | Rebellion Racing | Nicolas Prost
Neel Jani
Jeroen Bleekemolen | M Lola B10/60 Coupé-Toyota | No Time |
| 25 | 13 | LMP1 | M | Rebellion Racing | Andrea Belicchi
Jean-Christophe Boullion
Guy Smith | M Lola B10/60 Coupé-Toyota | No Time |
| 26 | 46 | LMP2 | M | TDS Racing | Mathias Beche
Pierre Thiriet
Jonathan Hirschi | Oreca 03-Nissan | No Time |
| 27 | 86 | GTP | M | Young Driver AMR | Tomas Enge
Alex Muller
Christoffer Nygaard
Johnathan Kennard | Aston Martin Vantage | No Time |
