| | No | Class | T | Team | Driver | Car | Time |
| 1 | 8 | LMP1 | M | Team Peugeot Total | Pedro Lamy Stephane Sarrazin | Peugeot 908 HDi-FAP | 1:40.726 |
| 2 | 7 | LMP1 | M | Team Peugeot Total | Marc Gene Nicolas Minassian | Peugeot 908 HDi-FAP | 1:41.296 |
| 3 | 1 | LMP1 | M | Audi Sport Team Joest | Allan McNish Rinaldo Capello | Audi R10 TDI | 1:41.607 |
| 4 | 2 | LMP1 | M | Audi Sport Team Joest | Alexandre Premat Mike Rockenfeller | Audi R10 TDI | 1:42.310 |
| 5 | 6 | LMP1 | M | Team Oreca Matmut | Olivier Panis Nicolas Lapierre | Courage-Oreca LC70-Judd | 1:44.070 |
| 5 | 10 | LMP1 | M | Charouz Racing System | Stefan Mucke Jan Charouz | Lola B06/80-Aston Martin | 1:44.116 |
| 6 | 5 | LMP1 | M | Team Oreca Matmut | Loic Duval Soheil Ayari Stepane Ortelli | Courage-Oreca LC70-Judd | 1:44.408 |
| 8 | 31 | LMP2 | D | Team Essex | John Nielsen Casper Elgaard | Porsche RS-Spyder | 1:44.645 |
| 9 | 16 | LMP1 | M | Pescarolo Sport | Emmanuel Collard Jean-Christophe Boullion | Pescarolo-Judd | 1:45.077 |
| 10 | 34 | LMP2 | M | Van Merksteijn Motorsport | Peter van Merksteijn Jos Verstappen Jeroen Bleekemolen | Porsche RS-Spyder | 1:45.214 |
| 11 | 17 | LMP1 | M | Pescarolo Sport | Harold Primat Christophe Tinseau | Pescarolo-Judd | 1:45.466 |
| 12 | 20 | LMP1 | M | Epsilon-Euskadi | Angel Burgueno Miguel Angel de Castro | Epsilon Euskadi-Judd | 1:46.189 |
| 13 | 21 | LMP1 | M | Epsilon-Euskadi | Shinji Nakano Adrian Valles | Epsilon Euskadi-Judd | 1:46.319 |
| 15 | 27 | LMP2 | M | Horag Racing | Fredy Lienhard Didier Theys Jan Lammers | Porsche RS-Spyder | 1:46.321 |
| 16 | 35 | LMP2 | M | Saulnier Racing | Pierre Ragues Matthieu Lahaye | Pescarolo-Judd | 1:46.408 |
| 17 | 45 | LMP2 | M | Embassy Racing | Warren Hughes Jonny Kane | WF01-Zytek | 1:46.620 |
| 18 | 18 | LMP1 | D | Rollcentre Racing | Joao Barbosa Vanina Ickx | Pescarolo-Judd | 1:46.761 |
| 19 | 25 | LMP2 | M | RML | Tommy Erdos Mike Newton | MG Lola EX265-MG | 1:46.810 |
| 20 | 33 | LMP2 | M | Speedy Racing Team Sebah | Andrea Belicchi Steve Zacchia Xavier Pompidou | Lola B08/80 Coupe-Judd | 1:46.862 |
| 21 | 32 | LMP2 | M | Barazi-Epsilon | Juan Barazi Michael Vergers Fernando Rees | Zytek 07S-Zytek | 1:46.917 |
| 22 | 46 | LMP2 | M | Embassy Racing | Darren Manning Joey Foster | WF01-Zytek | 1:46.994 |
| 23 | 15 | LMP1 | D | Creation AIM | Stuart Hall Jamie Campbell-Walter | Creation CA07-AIM | 1:47.837 |
| 24 | 40 | LMP2 | D | Quifel-ASM Team | Miguel Amaral Olivier Pla | Lola B050/40-AER | 1:47.909 |
| 25 | 4 | LMP1 | M | Saulnier Racing | Jacques Nicolet Marc Faggionato Richard Hein | Pescarolo-Judd | 1:48.744 |
| 26 | 44 | LMP2 | D | Kruse Schiller Motorsport | Jean de Pourtales Hideki Noda | Lola B05/40-Mazda | 1:49.382 |
| 26 | 14 | LMP1 | D | Creation AIM | Stephen Simpson Liz Halliday | Creation CA07-AIM | 1:49.585 |
| 27 | 41 | LMP2 | M | Trading Performance | Julien Schroyen Claude-Yves Gosselin Julien Schroyen | Zytek 07S-Zytek | 1:49.832 |
| 28 | 26 | LMP2 | D | Bruichladdich Radical | Marc Rostan Jens Petersen Jan-Dirk Lueders | Radical SR9 -AER | 1:51.565 |
| 29 | 37 | LMP2 | D | WR/Salini | Stephane Salini Philippe Salini Patrice Roussel | WR-Zytek | 1:53.857 |
| 30 | 59 | GT1 | M | Team Modena | Antonio Garcia Tomas Enge | Aston Martin DBR9 | 1:55.227 |
| 31 | 73 | GT1 | M | Luc Alphand Aventures | Olivier Beretta Jerome Policand Jean-Luc Blanchemain | Corvette C6.R | 1:56.258 |
| 32 | 72 | GT1 | M | Luc Alphand Aventures | Luc Alphand Guillaume Moreau Patrice Goueslard | Corvette C6.R | 1:56.766 |
| 33 | 55 | GT1 | M | IPB Spartak Racing | Roman Rusinov Peter Kox | Lamborghini Murcielago R-GT | 1:58.098 |
| 34 | 90 | GT2 | D | Farnbacher Racing | Pierre Ehret Pierre Kaffer Anthony Beltoise | Ferrari F430 GT | 1:58.525 |
| 35 | 77 | GT2 | M | Team Felbermayr Proton | Marc Lieb Alex Davison | Porsche 997 GT3 RSR | 1:58.624 |
| 36 | 76 | GT2 | M | IMSA Performance Matmut | Raymond Narac Richard Lietz | Porsche 997 GT3 RSR | 1:58.970 |
| 37 | 85 | GT2 | M | Snoras Spyker Squadron | Peter Dumbreck Ralf Kelleners Alexei Vasiliev | Spyker C8 Laviolette GT2R | 1:59.717 |
| 38 | 91 | GT2 | M | Farnbacher Racing | Lars Erik Nielsen Allan Simonsen Richard Westbrook | Porsche 997 GT3 RSR | 1:59.833 |
| 39 | 99 | GT2 | M | JMB Racing | Stephane Daoudi Ben Aucott | Ferrari F430 GT | 1:59.927 |
| 40 | 94 | GT2 | M | Speedy Racing Team | Andrea Chiesa Benjamin Leuenberger | Spyker C8 Laviolette GT2R | 2:00.774 |
| 41 | 96 | GT2 | D | Virgo Motorsport | Rob Bell Gianmaria Bruni | Ferrari F430 GT | 2:00.867 |
| 42 | 88 | GT2 | M | Team Felbermayr Proton | Horst Felbermayr Jr Christian Ried Horst Felbermayr Sr | Porsche 997 GT3 RSR | 2:02.628 |
| 43 | 75 | GT2 | M | IMSA Performance Matmut | Jean-Philippe Beloc Richard Balandras Michel Lecourt | Porsche 997 GT3 RSR | 2:02.765 |
| 44 | 98 | GT2 | M | JMB Racing | Peter Kutemann Maurice Basso | Ferrari F430 GT | 2:02.967 |
| 45 | 95 | GT2 | D | James Watt Automotive | Markus Palttala Tim Sugden Paul Daniels | Porsche 997 GT3 RSR | 2:04.457 |
| 46 | 3 | LMP1 | D | Scuderia Lavaggi | Wolfgang Kaufmann Giovanni Lavaggi | Lavaggi LS1 - AER | No Time |