| | No | Class | T | Team | Driver | Car | Time |
| 1 | 11 | LMP1 | M | Team Oreca Matmut-AIM | Olivier Panis
Nicolas Lapierre | Courage-Oreca LC70-AIM | 1:31.020 |
| 2 | 007 | LMP1 | M | Aston Martin Racing | Jan Charouz
Stefan Mücke
Tomas Enge | Lola Aston Martin | 1:31.160 |
| 3 | 10 | LMP1 | M | Team Oreca Matmut-AIM | Bruno Senna
Tiago Monteiro | Courage-Oreca LC70-AIM | 1:31.236 |
| 4 | 23 | LMP1 | M | Strakka Racing | Nick Leventis
Danny Watts | Ginetta-Zytek 09S-Zytek | 1:31.468 |
| 5 | 009 | LMP1 | M | Aston Martin Racing | Harold Primat
Darren Turner
Miguel Ramos | Lola Aston Martin | 1:31.556 |
| 6 | 15 | LMP1 | M | Kolles | Christian Bakkerud
Christijan Albers
Giorgio Mondini | Audi R10 TDI | 1:32.124 |
| 7 | 16 | LMP1 | M | Pescarolo Sport | Jean-Christophe Boullion
Christophe Tinseau | Pescarolo-Judd | 1:32.232 |
| 8 | 14 | LMP1 | M | Kolles | Andrew Meyrick
Charles Zwolsman
Narain Karthikeyan | Audi R10 TDI | 1:32.284 |
| 9 | 13 | LMP1 | M | Speedy Racing Team Sebah | Andrea Belicchi
Nicolas Prost
Marcel Fassler | Lola B06/80
Coupé-Aston Martin | 1:32.408 |
| 10 | 40 | LMP2 | D | Quifel-ASM Team | Miguel Amaral
Olivier Pla | Ginetta-Zytek 09S-Zytek | 1:34.296 |
| 11 | 12 | LMP1 | M | Signature Plus | Pierre Ragues
Frank Mailleux | Courage-Oreca LC70-Judd | 1:34.328 |
| 12 | 25 | LMP2 | M | RML | Tommy Erdos
Mike Newton | Lola B08/80 Coupé-Mazda | 1:34.728 |
| 13 | 41 | LMP2 | M | G.A.C. Racing Team | Karim Oijeh
Claude-Yves Gosselin
Philipp Peter | Zytek 07S-Zytek | 1:34.752 |
| 14 | 29 | LMP2 | M | Racing Box | Filippo Francioni
Andrea Ceccato
Giacomo Piccini | Lola B08/80 Coupé-Judd | 1:34.948 |
| 15 | 33 | LMP2 | M | Speedy Racing Team Sebah | Xavier Pompidou
Jonny Kane
Benjamin Leuenberger | Lola B08/80 Coupe-Judd | 1:35.100 |
| 16 | 30 | LMP2 | M | Racing Box | Andrea Piccini
Matteo Bobbi
Thomas Biagi | Lola B08/80 Coupé-Judd | 1:35.448 |
| 17 | 35 | LMP2 | D | Oak Racing | Matthieu Lahaye
Karim Ajlani | Pescarolo-Mazda | 1:37.076 |
| 18 | 37 | LMP2 | D | WR/Salini | Stéphane Salini
Philippe Salini
Bruce Jouanny | WR-Zytek | 1:37.088 |
| 19 | 24 | LMP2 | D | Oak Racing | Richard Hein
Jacques Nicolet | Pescarolo-Mazda | 1:38.396 |
| 20 | 43 | LMP2 | D | Q8 Oils Hache Team | Maximo Cortez
Carmen Jorda
Alfonso "Fonsi" Nieto | Lucchini-Judd | 1:39.296 |
| 21 | 28 | LMP2 | D | Ibanez Racing Service | José Ibanez
William Cavailhes
Frederic Da Rocha | Courage LC75 | 1:39.940 |
| 22 | 26 | LMP2 | D | Bruichladdich Bruneau | Pierre Bruneau
Tim Greaves
Francesco Sini | Radical SR9 -AER | 1:40.820 |
| 23 | 72 | GT1 | D | Luc Alphand Aventures | Julien Jousse
Patrice Goueslard
Yann Clairay | Corvette C6.R | 1:42.052 |
| 24 | 50 | GT1 | M | Larbre Competition | Roland Berville
Sébastien Dumez
Stéphane Lemeret | Saleen S7R-Ford | 1:44.028 |
| 25 | 77 | GT2 | M | Team Felbermayr Proton | Richard Lietz
Marc Lieb | Porsche 997 GT3 RSR | 1:44.804 |
| 26 | 92 | GT2 | D | JMW Motorsport | Rob Bell
Gianmaria Bruni | Ferrari F430 GT | 1:44.868 |
| 27 | 84 | GT2 | M | Team Modena | Antonio Garcia
Leo Mansell
Jaime Melo | Ferrari F430 GT | 1:45.436 |
| 28 | 76 | GT2 | M | IMSA Performance Matmut | Raymond Narac
Patrick Pilet | Porsche 997 GT3 RSR | 1:45.744 |
| 29 | 90 | GT2 | D | FBR | Pierre Ehret
Dominik Farnbacher
Anthony Beltoise | Ferrari F430 GT | 1:45.808 |
| 30 | 88 | GT2 | M | Team Felbermayr Proton | Horst Felbermayr Jr
Christian Ried
Francisco Cruz Martins | Porsche 997 GT3 RSR | 1:46.080 |
| 31 | 89 | GT2 | H | Hankook-Team Farnbacher | Allan Simonsen
Pierre Kaffer | Ferrari F430 GT | 1:46.380 |
| 32 | 87 | GT2 | M | Drayson Racing | Paul Drayson
Jonny Cocker | Aston Martin Vantage GT2 | 1:46.636 |
| 33 | 99 | GT2 | D | JMB Racing | John Hartshorne
Cesar Campanico
Albert von Thurn und Taxis | Ferrari F430 GT | 1:46.672 |
| 34 | 81 | GT2 | P | Easyrace | Maurice Basso
Roberto Plati
GianPaolo Tenchini | Ferrari F430 GT | 1:48.412 |
| 35 | 85 | GT2 | M | Snoras Spyker Squadron | Tom Coronel
Jarek Janis | Spyker C8 Laviolette GT2R | No time |
