| | No | Class | T | Team | Driver | Car | Time |
| 1 | 4 | LMP1 | M | Team Oreca Matmut | Olivier Panis
Nicolas Lapierre
Stéphane Sarrazin | Peugeot 908 HDi FAP | 1:33.046 |
| 2 | 12 | LMP1 | M | Rebellion Racing | Nicolas Prost
Neel Jani | Lola B10/60 Coupé-Rebellion | 1:35.583 |
| 3 | 13 | LMP1 | M | Rebellion Racing | Andrea Belicchi
Jean-Christophe Boullion | Lola B10/60 Coupé-Rebellion | 1:36.306 |
| 4 | 008 | LMP1 | D | Signature Plus | Pierre Ragues
Frank Mailleux
Vanina Ickx | Lola Aston Martin | 1:36.919 |
| 5 | 40 | LMP2 | D | Quifel-ASM Team | Miguel Amaral
Olivier Pla | Ginetta-Zytek 09S-Zytek | 1:37.503 |
| 6 | 42 | LMP2 | M | Strakka Racing | Nick Leventis
Danny Watts
Jonny Kane | HPD ARX-01 | 1:38.347 |
| 7 | 25 | LMP2 | D | RML | Tommy Erdos
Mike Newton
Ben Collins | Lola HPD Coupé | 1:39.285 |
| 8 | 35 | LMP2 | D | Oak Racing | Richard Hein
Guillaume Moreau | Pescarolo-Judd | 1:39.433 |
| 9 | 41 | LMP2 | D | Team Bruichladdich | Karim Oijeh
Tim Greaves
Thor-Chrsitian Ebbesvik | Ginetta-Zytek 09S-Zytek | 1:39.622 |
| 10 | 24 | LMP2 | D | Oak Racing | Matthieu Lahaye
Jacques Nicolet | Pescarolo-Judd | 1:40.161 |
| 11 | 44 | FLM | M | DAMS | Jody Firth
Warren Hughes | Formula Le Mans-Oreca - 09 | 1:42.291 |
| 12 | 49 | FLM | M | Applewood Seven | Damien Toulemonde
Mathias Beche | Formula Le Mans-Oreca - 09 | 1:43.579 |
| 13 | 43 | FLM | M | DAMS | Andrea Barlesi
Alessandro Cicognani
Gary Chalandon | Formula Le Mans-Oreca - 09 | 1:43.839 |
| 14 | 48 | FLM | M | Hope Polevision Racing | Christophe Pillon
Vincent Capillaire
Nico Verdonck | Formula Le Mans | 1:44.252 |
| 15 | 47 | FLM | M | Hope Polevision Racing | Luca Moro
Steve Zacchia
Olivier Lombard | Formula Le Mans | 1:44.413 |
| 16 | 89 | GT2 | H | Hankook-Team Farnbacher | Dominik Farnbacher
Allan Simonsen | Ferrari F430 GT | 1:46.658 |
| 17 | 36 | LMP2 | D | Pegasus Racing | Julien Schell
Frederic Da Rocha | Courage LC75 AER | 1:46.684 |
| 18 | 96 | GT2 | M | AF Corse | Gianmaria Bruni
Jaime Melo | Ferrari F430 GT | 1:46.694 |
| 19 | 75 | GT2 | M | Prospeed Competition | Marco Holzer
Richard Westbrook | Porsche 997 GT3 RSR | 1:46.905 |
| 20 | 76 | GT2 | M | IMSA Performance Matmut | Raymond Narac
Patrick Pilet | Porsche 997 GT3 RSR | 1:46.924 |
| 21 | 95 | GT2 | M | AF Corse | Giancarlo Fisichella
Toni Vilander
Jean Alesi | Ferrari F430 GT | 1:46.951 |
| 22 | 91 | GT2 | M | CRS Racing | Andrew Kirkaldy
Tim Mullen | Ferrari F430 GT | 1:47.130 |
| 23 | 45 | FLM | M | Boutsen Energy Racing | Dominik Kraihamer
Nicolas De Crem
Bernard Delhez | Formula Le Mans-Oreca - 09 | 1:47.172 |
| 24 | 88 | GT2 | M | Team Felbermayr Proton | Martin Ragginger
Christian Ried
Wolf Henzler | Porsche 997 GT3 RSR | 1:47.226 |
| 25 | 85 | GT2 | M | Spyker Squadron | Peter Dumbreck
Jeroen Bleekemolen | Spyker C8 Laviolette GT2-R | 1:47.334 |
| 26 | 66 | GT1 | M | Atlas FX-Team FS | Julien Schroyen
Carlo Van Dam
Adam Lacko | Saleen S7-R | 1:47.364 |
| 27 | 77 | GT2 | M | Team Felbermayr Proton | Marc Lieb
Richard Lietz | Porsche 997 GT3 RSR | 1:47.655 |
| 28 | 46 | FLM | M | JMB Racing | Peter Kutemann
Maurice Basso
John Hartshorne | Formula Le Mans-Oreca - 09 | 1:47.808 |
| 29 | 94 | GT2 | M | AF Corse | Luis Perez Companc
Matias Russo | Ferrari F430 GT | 1:48.112 |
| 30 | 90 | GT2 | M | CRS Racing | Pierre Ehret
Phil Quaife
Pierre Kaffer | Ferrari F430 GT | 1:48.121 |
| 31 | 50 | GT1 | M | Larbre Competition | Gabriel Gardel
Patrice Goueslard
Fernando Rees | Saleen S7-R | 1:48.571 |
| 32 | 92 | GT2 | D | JMW Motorsport | Rob Bell
Darren Turner | Aston Martin V8 Vantage | No Time |
