| | No | Class | T | Team | Driver | Car | Time |
| 1 | 7 | LMP1 | M | Audi Sport Team Joest | Dindo Capello
Allan McNish | Audi R15 TDI | 1:42.053 |
| 2 | 4 | LMP1 | M | Team Oreca Matmut | Olivier Panis
Nicolas Lapierre
Stephane Sarrazin | Peugeot 908 HDi FAP | 1:42.904 |
| 3 | 009 | LMP1 | M | Aston Martin Racing | Adrian Fernandez
Harold Primat
Stefan Mücke | Lola Aston Martin | 1:43.428 |
| 4 | 13 | LMP1 | M | Rebellion Racing | Andrea Belicchi
Jean-Christophe Boullion
Guy Smith | Lola B10/60
Coupé-Rebellion | 1:43.911 |
| 5 | 6 | LMP1 | D | Team Oreca Matmut | Soheil Ayari
Loic Duval
Didier Andre | Oreca 01-AIM | 1:44.454 |
| 6 | 12 | LMP1 | M | Rebellion Racing | Nicolas Prost
Neel Jani | Lola B10/60
Coupé-Rebellion | 1:44.764 |
| 7 | 008 | LMP1 | D | Signature Plus | Pierre Ragues
Frank Mailleux
Vanina Ickx | Lola Aston Martin | 1:44.963 |
| 8 | 42 | LMP2 | M | Strakka Racing | Nick Leventis
Danny Watts
Jonny Kane | HPD ARX-01 | 1:45.878 |
| 9 | 5 | LMP1 | D | Beechdean Mansell | Nigel Mansell
Leo Mansell
Greg Mansell | Ginetta-Zytek
GZ09S-Zytek | 1:46.223 |
| 10 | 25 | LMP2 | D | RML | Tommy Erdos
Mike Newton
Andy Wallace | Lola HPD Coupé | 1:47.106 |
| 11 | 41 | LMP2 | D | Team Bruichladdich | Karim Oijeh
Tim Greaves
Thor-Chrsitian Ebbesvik | Ginetta-Zytek 09S-Zytek | 1:47.646 |
| 12 | 40 | LMP2 | D | Quifel-ASM Team | Miguel Amaral
Olivier Pla
Warren Hughes | Ginetta-Zytek 09S-Zytek | 1:48.106 |
| 13 | 35 | LMP2 | D | Oak Racing | Richard Hein
Guillaume Moreau | Pescarolo-Judd | 1:48.539 |
| 14 | 24 | LMP2 | D | Oak Racing | Matthieu Lahaye
Jacques Nicolet | Pescarolo-Judd | 1:49.422 |
| 15 | 30 | LMP2 | P | Racing Box | Ferdinando Geri
Andrea Piccini
Giacomo Piccini | Lola B09 Coupé-Judd | 1:50.498 |
| 16 | 29 | LMP2 | P | Racing Box | Marco Cioci
Piergiuseppe Perazzini
Luca Pirri | Lola B09 Coupé-Judd | 1:50.600 |
| 17 | 37 | LMP2 | D | WR/Salini | Philippe Salini
Stéphane Salini
Tristan Gommendy | WR-Zytek | 1:52.049 |
| 18 | 39 | LMP2 | D | KSM | Jean De Pourtales
Hideki Noda
Jonathan Kennard | Lola B08/47-Judd | 1:52.233 |
| 19 | 27 | LMP2 | D | Race Performance | Michel Frey
Ralph Meichtry
Tyler Dueck | Radical SR9 -Judd | 1:53.006 |
| 20 | 48 | FLM | M | Hope Polevision Racing | Mathias Beche
Christophe Pillon
Vincent Capillaire | Formula Le Mans-
Oreca - 09 | 1:54.558 |
| 21 | 44 | FLM | M | DAMS | Dean Stirling
Luke Hines
Edoardo Piscopo | Formula Le Mans-
Oreca - 09 | 1:54.600 |
| 22 | 45 | FLM | M | Boutsen Energy Racing | Dominik Kraihamer
Nicolas De Crem
Bernard Delhez | Formula Le Mans-
Oreca - 09 | 1:54.651 |
| 23 | 47 | FLM | M | Hope Polevision Racing | Steve Zacchia
Luca Moro
Wolfgang Kaufmann | Formula Le Mans-
Oreca - 09 | 1:55.315 |
| 24 | 43 | FLM | M | DAMS | Andrea Barlesi
Alessandro Cicognani
Gary Chalandon | Formula Le Mans-
Oreca - 09 | 1:55.476 |
| 25 | 36 | LMP2 | D | Pegasus Racing | Julien Schell
Jean-Christophe Metz
Frederic Da Rocha | Courage-Oreca
LC75 - AER | 1:55.680 |
| 26 | 49 | FLM | M | Applewood Seven | Damien Toulemonde
David Zollinger
Ross Zampatti | Formula Le Mans-
Oreca - 09 | 1:56.406 |
| 27 | 50 | GT1 | M | Larbre Competition | Gabriel Gardel
Patrice Goueslard
Julien Canal | Saleen S7R | 1:56.987 |
| 28 | 77 | GT2 | M | Team Felbermayr Proton | Marc Lieb
Richard Lietz | Porsche 997 GT3 RSR | 1:58.192 |
| 29 | 95 | GT2 | M | AF Corse | Giancarlo Fisichella
Toni Vilander
Jean Alesi | Ferrari F430 GT | 1:58.254 |
| 30 | 91 | GT2 | M | CRS Racing | Andrew Kirkaldy
Tim Mullen | Ferrari F430 GT | 1:58.323 |
| 31 | 90 | GT2 | M | CRS Racing | Pierre Ehret
Phil Quaife
Pierre Kaffer | Ferrari F430 GT | 1:58.344 |
| 32 | 94 | GT2 | M | AF Corse | Luis Perez Companc
Matias Russo | Ferrari F430 GT | 1:58.412 |
| 33 | 96 | GT2 | M | AF Corse | Gianmaria Bruni
Jaime Melo | Ferrari F430 GT | 1:58.458 |
| 34 | 92 | GT2 | D | JMW Motorsport | Rob Bell
Darren Turner | Aston Martin V8 Vantage | 1:58.558 |
| 35 | 75 | GT2 | M | Prospeed Competition | Marco Holzer
Richard Westbrook | Porsche 997 GT3 RSR | 1:58.911 |
| 36 | 85 | GT2 | M | Spyker Squadron | Peter Dumbreck
Tom Coronel
Jeroen Bleekemolen | Spyker C8 Laviolette GT2-R | 1:58.955 |
| 37 | 76 | GT2 | M | IMSA Performance Matmut | Raymond Narac
Patrick Pilet | Porsche 997 GT3 RSR | 1:59.673 |
| 38 | 88 | GT2 | M | Team Felbermayr Proton | Martin Ragginger
Christian Ried
Patrick Long | Porsche 997 GT3 RSR | 1:59.678 |
| 39 | 89 | GT2 | H | Hankook-Team Farnbacher | Dominik Farnbacher
Allan Simonsen | Ferrari F430 GT | 1:59.777 |
| 40 | 78 | GT2 | D | BMW Team Schnitzer | Jörg Müller
Dirk Werner | BMW M3 | 2:00.010 |
| 41 | 46 | FLM | M | JMB Racing | Peter Kutemann
Maurice Basso
John Hartshorne | Formula Le Mans-Oreca - 10 | 2:01.407 |
