| | No | Class | T | Team | Driver | Car | Time |
| 1 | 7 | LMP1 | M | Audi Sport Team Joest | Tom Kristensen
Allan McNish | Audi R15 TDI | 1:46.259 |
| 2 | 1 | LMP1 | M | Team Peugeot Total | Anthony Davidson
Nic Minassian | Peugeot 908 HDi FAP | 1:46.698 |
| 3 | 12 | LMP1 | M | Rebellion Racing | Nicolas Prost
Neel Jani | Lola B10/60 Coupé-Rebellion | 1:46.926 |
| 4 | 4 | LMP1 | M | Team Oreca Matmut | Nicolas Lapierre
Stéphane Sarrazin | Peugeot 908 HDi FAP | 1:46.976 |
| 5 | 8 | LMP1 | M | Audi Sport Team Joest | Timo Bernhard
Dindo Capello | Audi R15 TDI | 1:48.732 |
| 6 | 13 | LMP1 | M | Rebellion Racing | Andrea Belicchi
Jean-Christophe Boullion | Lola B10/60 Coupé-Rebellion | 1:49.094 |
| 7 | 009 | LMP1 | M | Aston Martin Racing | Juan Barazi
Sam Hancock
Stefan Mucke | Lola Aston Martin | 1:49.107 |
| 8 | 007 | LMP1 | M | Aston Martin Racing | Adrian Fernandez
Harold Primat
Andy Meyrick | Lola Aston Martin | 1:49.237 |
| 9 | 42 | LMP2 | M | Strakka Racing | Nick Leventis
Danny Watts
Jonny Kane | HPD ARX-01 | 1:49.525 |
| 10 | 008 | LMP1 | D | Signature Plus | Pierre Ragues
Frank Mailleux
Vanina Ickx | Lola Aston Martin | 1:50.663 |
| 11 | 5 | LMP1 | D | Beechdean Mansell | Nigel Mansell
Leo Mansell
Greg Mansell | Ginetta-Zytek 09S | 1:51.009 |
| 12 | 35 | LMP2 | D | Oak Racing | Richard Hein
Guillaume Moreau | Pescarolo-Judd | 1:51.445 |
| 13 | 41 | LMP2 | D | Team Bruichladdich | Karim Oijeh
Tim Greaves
Thor-Chrsitian Ebbesvik | Ginetta-Zytek 09S-Zytek | 1:52.314 |
| 14 | 25 | LMP2 | D | RML | Tommy Erdos
Mike Newton
Ben Collins | Lola HPD Coupé | 1:53.092 |
| 15 | 40 | LMP2 | D | Quifel-ASM Team | Miguel Amaral
Olivier Pla | Ginetta-Zytek 09S-Zytek | 1:53.823 |
| 16 | 24 | LMP2 | D | Oak Racing | Matthieu Lahaye
Jacques Nicolet | Pescarolo-Judd | 1:54.538 |
| 17 | 20 | LMP1 | M | Team LNT | Tony Burgess
Johnny Mowlem
Chris McMurry | Ginetta-Zytek 09S | 1:54.645 |
| 18 | 29 | LMP2 | P | MIK Racing | Piergiuseppe Perazzini
Marco Cioci
Luca Pirri | Lola B09 Coupé-Judd | 1:55.961 |
| 19 | 11 | LMP1 | M | Drayson Racing | Paul Drayson
Jonny Cocker | Lola B10/60 Coupé-Judd | 1:57.480 |
| 20 | 30 | LMP2 | P | MIK Racing | Fabio Babini
Ferdinando Geri
Federico Leo | Lola B09 Coupé-Judd | 1:58.256 |
| 21 | 31 | LMP2 | D | Team RLR MSport | Barry Gates
Rob Garofall
Simon Phillips | MG Lola EX265-AER | 1:58.839 |
| 22 | 48 | FLM | M | Hope Polevision Racing | Christophe Pillon
Nico Verdonck
Charlie Hollings | Formula Le Mans | 2:00.566 |
| 23 | 27 | LMP2 | D | Race Performance | Michel Frey
Marc Rostan
Pierre Bruneau | Radical SR9 -Judd | 2:00.740 |
| 24 | 45 | FLM | M | Boutsen Energy Racing | Dominik Kraihamer
Nicolas De Crem
Bernard Delhez | Formula Le Mans-Oreca - 09 | 2:01.193 |
| 25 | 44 | FLM | M | DAMS | Jody Firth
Warren Hughes | Formula Le Mans-Oreca - 09 | 2:01.274 |
| 26 | 39 | LMP2 | D | KSM | Jean De Pourtales
Lucas Ordoñez
Jonathan Kennard | Lola B08/47-Judd | 2:02.735 |
| 27 | 47 | FLM | M | Hope Polevision Racing | Luca Moro
Steve Zacchia
Olivier Lombard | Formula Le Mans | 2:03.132 |
| 28 | 50 | GT1 | M | Larbre Competition | Gabriel Gardel
Patrice Goueslard
Fernando Rees | Saleen S7R | 2:03.749 |
| 29 | 75 | GT2 | M | Prospeed Competition | Marco Holzer
Richard Westbrook | Porsche 997 GT3 RSR | 2:04.431 |
| 30 | 36 | LMP2 | D | Pegasus Racing | Julien Schell
Frederic Da Rocha | Courage-Oreca LC75 - AER | 2:04.627 |
| 31 | 78 | GT2 | D | BMW Team Schnitzer | Jörg Müller
Dirk Werner | BMW M3 | 2:04.788 |
| 32 | 88 | GT2 | M | Team Felbermayr Proton | Martin Ragginger
Christian Ried
Romain Dumas | Porsche 997 GT3 RSR | 2:05.141 |
| 33 | 77 | GT2 | M | Team Felbermayr Proton | Marc Lieb
Richard Lietz | Porsche 997 GT3 RSR | 2:05.313 |
| 34 | 76 | GT2 | M | IMSA Performance Matmut | Raymond Narac
Patrick Pilet | Porsche 997 GT3 RSR | 2:05.545 |
| 35 | 92 | GT2 | D | JMW Motorsport | Rob Bell
Darren Turner | Aston Martin V8 Vantage | 2:05.828 |
| 36 | 95 | GT2 | M | AF Corse | Giancarlo Fisichella
Toni Vilander
Jean Alesi | Ferrari F430 GT | 2:05.971 |
| 37 | 43 | FLM | M | DAMS | Andrea Barlesi
Alessandro Cicognani
Gary Chalandon | Formula Le Mans-Oreca - 09 | 2:06.079 |
| 38 | 91 | GT2 | M | CRS Racing | Andrew Kirkaldy
Tim Mullen | Ferrari F430 GT | 2:06.161 |
| 39 | 96 | GT2 | M | AF Corse | Gianmaria Bruni
Jaime Melo | Ferrari F430 GT | 2:06.303 |
| 40 | 94 | GT2 | M | AF Corse | Luis Perez Companc
Matias Russo | Ferrari F430 GT | 2:06.532 |
| 41 | 90 | GT2 | M | CRS Racing | Pierre Ehret
Phil Quaife
Pierre Kaffer | Ferrari F430 GT | 2:07.018 |
| 42 | 85 | GT2 | M | Spyker Squadron | Peter Dumbreck
Tom Coronel | Spyker C8 Laviolette GT2-R | 2:07.079 |
| 43 | 89 | GT2 | H | Hankook-Team Farnbacher | Dominik Farnbacher
Allan Simonsen | Ferrari F430 GT | 2:07.345 |
| 44 | 46 | FLM | M | JMB Racing | Peter Kutemann
Maurice Basso
John Hartshorne | Formula Le Mans-Oreca - 10 | 2:09.320 |
| 45 | 99 | GT2 | TBA | Gulf Team First | Fabien Giroix
Roald Goethe | Lamborghini LP560 | 2:34.041 |
| 46 | 49 | FLM | M | Applewood Seven | Damien Toulemonde
Mathias Beche | Formula Le Mans-Oreca - 09 | No Time |
| 47 | 66 | GT1 | M | Atlas FX-Team FS | Carlo van Dam
Zsolt Baumgartner
James Winslow | Saleen S7R | No Time |
