| | No | Class | T | Team | Driver | Car | Time |
| 1 | 2 | LMP1 | M | Team Peugeot Total | Nicolas Minassian
Stéphane Sarrazin
Franck Montagny | Peugeot 908 HDi-FAP | 3:20.034 |
| 2 | 3 | LMP1 | M | Peugeot Sport Total | Sebastien Bourdais
Pedro Lamy
Simon Pagenaud | Peugeot 908 HDi-FAP | 3:21.266 |
| 3 | 4 | LMP1 | M | Team Oreca Matmut | Olivier Panis
Nicolas Lapierre
Loic Duval | Peugeot 908 HDi-FAP | 3:21.514 |
| 4 | 1 | LMP1 | M | Team Peugeot Total | Alexander Wurz
Marc Gené
Anthony Davidson | Peugeot 908 HDi-FAP | 3:23.605 |
| 5 | 7 | LMP1 | M | Audi Sport Team Joest | Tom Kristensen
Dindo Capello
Allan McNish | Audi R15 TDI | 3:23.935 |
| 6 | 8 | LMP1 | M | Audi Sport Team Joest | Andre Lotterer
Marcel Fassler
Benoit Treluyer | Audi R15 TDI | 3:24.099 |
| 7 | 9 | LMP1 | M | Audi Sport North America | Mike Rockenfeller
Timo Bernhard
Romain Dumas | Audi R15 TDI | 3:24.779 |
| 8 | 009 | LMP1 | M | Aston Martin Racing | Darren Turner
Juan Barazi
Sam Hancock | Lola Aston Martin | 3:27.268 |
| 9 | 007 | LMP1 | M | Aston Martin Racing | Harold Primat
Stefan Mücke
Adrian Fernandez | Lola Aston Martin | 3:28.133 |
| 10 | 13 | LMP1 | M | Rebellion Racing | Andrea Belicchi
Jean Christophe Bouillon
Guy Smith | Lola B10/60-Rebellion Coupé | 3:29.851 |
| 11 | 14 | LMP1 | M | Kolles | Christophe Bouchut
Scott Tucker
Manuel Rodrigues | Audi R10 TDI | 3:30.295 |
| 12 | 12 | LMP1 | M | Rebellion Racing | Nicolas Prost
Neel Jani
Marco Andretti | Lola B10/60-Rebellion Coupé | 3:30.269 |
| 13 | 6 | LMP1 | D | AIM Team Oreca Matmut | Soheil Ayari
Didier Andre
Andy Meyrick | Oreca 01 AIM | 3:30.761 |
| 14 | 15 | LMP1 | M | Kolles | Christian Bakkerud
Oliver Jarvis
Christijan Albers | Audi R10 TDI | 3:32.853 |
| 15 | 008 | LMP1 | D | Signature Plus | Pierre Ragues
Vanina Ickx
Franck Mailleux | Lola Aston Martin | 3:33.067 |
| 16 | 5 | LMP1 | D | Beechdean Mansell | Nigel Mansell
Greg Mansell
Leo mansell | Ginetta-Zytek 09S-Zytek | 3:34.857 |
| 17 | 11 | LMP1 | M | Drayson Racing | Paul Drayson
Jonny Cocker
Emanuele Pirro | Lola B09/60-Judd Coupé | 3:37.416 |
| 18 | 26 | LMP2 | M | Highcroft Racing | David Brabham
Mario Franchitti
Marco Werner | HPD ARX.01c-HPD | 3:38.691 |
| 19 | 42 | LMP2 | M | Strakka Racing | Nick Leventis
Danny Watts
Jonny Kane | HPD ARX.01-HPD | 3:38.825 |
| 20 | 25 | LMP2 | D | RML | Tommy Erdos
Mike Newton
Andy Wallace | Lola HPD Coupé | 3:40.119 |
| 21 | 40 | LMP2 | D | Quifel-ASM Team | Miguel Amaral
Olivier Pla
Warren Hughes | Ginetta-Zytek 09S-Zytek | 3:42.351 |
| 22 | 35 | LMP2 | D | Oak Racing | Matthieu Lahaye
Guillaume Moreau
Jan Charouz | Pescarolo-Judd | 3:44.178 |
| 23 | 29 | LMP2 | P | Racing Box | Luca Pirri
Marco Cioci
Piergiuseppe Perazzini | Lola B09-Judd Coupé | 3:49.938 |
| 24 | 24 | LMP2 | D | Oak Racing | Jaques Nicolet
Richard Hein
Jean-François Yvon | Pescarolo-Judd | 3:50.853 |
| 25 | 41 | LMP2 | D | Team Bruichladdich | Karim Oijeh
Tim Greaves
Gary Chalandon | Ginetta-Zytek 09S-Zytek | 3:51.358 |
| 26 | 39 | LMP2 | M | KSM | Jean de Pourtales
Hideki Noda
Johnathan Kennard | Lola B08/47-Judd | 3:52.353 |
| 27 | 28 | LMP2 | | Race Performance PR | Marc Rostan
Ralph Meichtry
Pierre Bruneau | Radical Judd SR9 | 3:53.773 |
| 28 | 52 | GT1 | M | Young Driver AMR | Christoffer Nygaard
Tomas Enge
Peter Kox | Aston Martin DBR9 | 3:56.839 |
| 29 | 37 | LMP2 | D | Gerard Welter | Philippe Salini
Stéphane Salini
Tristan Gommendy | WR-Zytek | 3:56.918 |
| 30 | 72 | GT1 | D | Luc Alphand Aventures | Stephane Gregoire
Jérôme Policand
David Hart | Corvette C6.R | 3:59.752 |
| 31 | 64 | GT2 | M | Corvette Racing | Oliver Gavin
Olivier Beretta
Emmanuel Collard | Chevrolet Corvette C6 ZR1 | 4:00.888 |
| 32 | 70 | GT1 | M | Marc VDS Racing Team | Eric de Doncker
Bas Leinders
Markus Paltalla | Ford GT | 4:01.665 |
| 33 | 38 | LMP2 | D | Pegasus Racing | Julien Schell
Frédéric Da Rocha
David Zollinger | Norma-Judd | 4:01.809 |
| 34 | 77 | GT2 | M | Team Felbermayr Proton | Marc Lieb
Richard Lietz
Wolf Henzler | Porsche 997 GT3 RSR | 4:02.101 |
| 35 | 63 | GT2 | M | Corvette Racing | Jan Magnussen
Johnny O'Connell
Antonio Garcia | Chevrolet Corvette C6 ZR1 | 4:02.187 |
| 36 | 60 | GT1 | M | Matech Competition | Natacha Gachnang
Rahel Frey
Cyndie Allemann | Ford GT | 4:02.546 |
| 37 | 82 | GT2 | M | Risi Competizione | Jaime Melo
Gimmi Bruni
Pierre Kaffer | Ferrari F430 GT | 4:03.007 |
| 38 | 89 | GT2 | H | Hankook-Team Farnbacher | Dominik Farnbacher
Allan Simonsen
Leh Keen | Ferrari F430 GT | 4:03.046 |
| 39 | 50 | GT1 | M | Larbre Competition | Roland Berville
Julien Canal
Gabriele Gardel | Saleen S7R | 4:03.142 |
| 40 | 85 | GT2 | M | Spyker Squadron | Tom Coronel
Peter Dumbreck
Jeroen Bleekemolen | Spyker C8 Laviolette GT2-R | 4:03.336 |
| 41 | 95 | GT2 | M | AF Corse SRL | Giancarlo Fisichella
Jean Alesi
Toni Vilander | Ferrari F430 GT | 4:03.643 |
| 42 | 73 | GT1 | D | Luc Alphand Aventures | Julien Jousse
Xavier Maassen
Patrice Goueslard | Corvette C6.R | 4:03.879 |
| 43 | 97 | GT2 | M | BMS Scuderia Italia SPA | Marco Holzer
Richard Westbrook
Timo Scheider | Porsche 997 GT3 RSR | 4:04.098 |
| 44 | 96 | GT2 | M | AF Corse | Luis Perez Companc
Matias Russo
Mika Salo | Ferrari F430 GT | 4:04.476 |
| 45 | 76 | GT2 | M | IMSA Performance Matmut | Raymond Narac
Patrick Pilet
Patrick Long | Porsche 997 GT3 RSR | 4:04.849 |
| 46 | 61 | GT1 | M | Matech Competition | Thomas Mutsch
Romain Grosjean
Jonathan Hirschi | Ford GT | 4:05.295 |
| 47 | 78 | GT2 | D | BMW Motorsport | Jörg Müller
Augusto Farfus
Uwe Alzen | BMW E92 M3 | 4:05.675 |
| 48 | 79 | GT2 | D | BMW Motorsport | Andy Priaulx
Dirk Müller
Dirk Werner | BMW E92 M3 | 4:05.876 |
| 49 | 80 | GT2 | M | Flying Lizard Motorsport | Seth Neiman
Darren Law
Jörg Bergmeister | Porsche 997 GT3 RSR | 4:06.564 |
| 50 | 92 | GT2 | D | JMW Motorsport | Rob Bell
Tim Sugden
Bryce Miller | Aston Martin Vantage | 4:08.634 |
| 51 | 88 | GT2 | M | Team Felbermayr-Proton | Horst Felbermayr Snr
Horst Felbermayr Jr
Miro Konopka | Porsche 997 GT3 RSR | 4:10.953 |
| 52 | 83 | GT2 | M | Risi Competizione | Tracey Krohn
Nic Jonsson
Eric van de Poele | Ferrari F430 GT | 4:10.615 |
| 53 | 69 | GT1 | Y | JLOC | Atsushi Yogo
Koji Yamanishi
Hiroyuki Iiri | Lamborghini Murcielago | 4:14.448 |
| 54 | 75 | GT2 | M | Prospeed Competition | Paul van Splunteren
Niek Hommerson
Louis Machiels | Porsche 997 GT3 RSR | 4:17.011 |
| 55 | 81 | GT2 | Y | Jaguar RSR | Paul Gentilozzi
Ryan Dalziel
Marc Goossens | Jaguar XKRS | 4:17.668 |
| 56 | 19 | LMP1 | D | Michael Lewis/Autocon | Michael Lewis
Bryan Willman
Tony Burgess | Lola B06/10-AER | 8:14.587 |
